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424   Industrial Wastewater Treatment, Recycling, and Reuse


             800
                                                             Feed COD
             700                                             Bioreactor COD
                                                             Permeate COD
             600

             500
            COD (mg/L)  400


             300

             200
             100

               0
                0   5  10  15  20  25  30  35  40  45  50  55  60  65  70  75  80  85
                                        Days of operation
          Figure 10.14 Evolution of concentrations of COD in the feed, bioreactor, and permeate
          during the performance evaluation of the AnMBR.


          385 mg/L. The average residual COD, TOC, and BOD 5 concentrations in
          the permeate were 20, 7, and 8, respectively. Because there is a considerable
          difference in COD concentration for reactor content and permeate, the used
          ultra-filtration membrane might be rejecting a considerable amount of
          organics available in the reactor during filtration.
             The COD and TOC removal performance of the AnMBR is shown in
          Figures 10.15 and 10.16, respectively. After stabilization of the AnMBR, the
          TSS, COD, TOC, and BOD 5 average removals were 100%, 95%, 95%, and
          97%, respectively.
             Figure 10.17 shows the concentrations of BOD 5 in the effluent during
          this phase of performance evaluation of the AnMBR. The average concen-
          tration of BOD 5 for the feed was 247 mg/L, whereas BOD 5 concentration
          in the permeate was 8 mg/L.


          10.4.3.2.2 Biogas Generation and Yield
          After stabilization of biological performance, the biogas generation from
          the AnMBR was studied on a daily basis, and is illustrated in Figure 10.18.
          A gas leak test was carried out for the bioreactor, gas piping, and gas storage
          unit before starting the experiment. Biogas generation varied from 229 to
          281 L/day with an average generation of 264 L/day. As indicated in
          Figure 10.18, the observed biogas generation and biogas yield were very
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