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5.2 Piezoelectricity                                                           89

                  metal foil strain gauges. The adhesives can contribute to a phenomenon called
                  creep, whereby the gauge can effectively slip and therefore produce false readings as
                  the adhesive softens with increasing temperature or over long periods of time.
                      Thick-film resistors, often used in hybrid circuits, have also been shown to be
                  piezoresistive. Their gauge factor is around 10, and therefore, they offer a sensitivity
                  between that of a semiconductor and foil strain gauge. The TCR is around 100 parts
                  per million (ppm) per degree Celsius and matching between adjacent resistors is
                  often less that 10 ppm/°C, making them well suited for use as active elements in
                  Wheatstone bridge circuits, which reduce the overall temperature sensitivity.
                      An associated effect that has been observed in semiconductors is the so-called
                  piezojunction effect, whereby a shift in the I-V characteristic of a p-n junction is
                  observed as a result of an applied stress. Although this is an interesting physical
                  effect, it has found little use in commercial micromachined devices.



            5.2   Piezoelectricity

                  Certain classes of crystal exhibit the property of producing an electric charge when
                  subjected to an applied mechanical force (direct effect). They also deform in
                  response to an externally applied electric field (inverse effect). This is an unusual
                  effect as the material can act as both a sensor and actuator. It was first discovered in
                  quartz by Jacques and Pierre Curie in 1880. The physical origin of piezoelectricity
                  arises because of charge asymmetry within the crystal structure. Such crystals are
                  often termed noncentrosymmetric, and because of the lack of symmetry, they have
                  anisotropic characteristics. Owing to its symmetric, cubic crystal structure, silicon is
                  not, therefore, piezoelectric. Some crystals such as quartz and Rochelle salt are
                  naturally occurring piezoelectrics, while others like the ceramic materials barium
                  titanate, lead zirconate titanate (PZT), and the polymer material polyvinylidene
                  fluoride (PVDF) are ferroelectric. Ferroelectric materials are those that exhibit
                  spontaneous polarization upon the application of an applied electric field. In other
                  words, ferroelectrics must be poled (polarized) in order to make them exhibit
                  piezoelectric behavior. They are analogous to ferromagnetic materials in many
                  respects. Figure 5.3 shows how an applied force gives rise to an electric charge (and
                  hence voltage) across the faces of a slab of piezoelectric material.





                                                                3 (direction of polarization)
                                  Piezoelectric material
                                                                     2

                                                  Applied force
                                                                       1

                              V                              Metal electrodes



                  Figure 5.3  An illustration of the piezoelectric effect. The applied force results in the generation of
                  a voltage across the electrodes.
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