Page 249 - Mechanism and Theory in Organic Chemistry

Table 5.6 FORMATION REACTIONS CARBOCATIONS
OF
AND

R-X - + X-
R+
-,Bond heterolysisa
R-X+ + R+ +X
Addition to GCb

Addition to C=OC

Reactions Regenerating Carbocations
Hydrogen transferd

Reactions Destroying Carbocations
R+ + Y:- -
Combination with Lewis basea
RY

a Chapter 5.
Chapter 7.
Chapter 8.
C. D. Nenitzescu, in Carbonium Ions, G. A. Olah and P. v. R. Schleyer, Eds., Wiley-Interscience,
New York, 1970, Vol. 11, p. 463; see also D. M. Brouwer and H. Hogeveen, pro^. Phys. Or& Chem.,
9, 179 (1972), who also review the following less commonly encountered electrophilic substitution
reactions:
R-H + H+ + R+ + Hz
Rl-R2 + H+ Rl + R2-H
Rl+ + Rz-R3 + R1-R2 + R3+
Chapter 6.