Page 250 - Multifunctional Photocatalytic Materials for Energy
P. 250
Photocatalysts for hydrogen generation and organic contaminants degradation 233
The use of platinum on active catalysts for hydrogen evolution has been proposed
and tested because of platinum’s selectivity toward hydrogen and lowering its disso-
ciation potential. However, the future direction of photocatalytic hydrogen evolution
will focus more on designing a new platinum-free catalyst with band edges matching
those of the redox potentials of water and with a rapid charge transfer by maintaining
physical and photochemical stability. For a photocatalyst, efficiency along with reuse
and recyclability are equally crucial and can be achieved by the immobilization of
photocatalysts on templates/polymers. All these efforts will be vital in establishing
photocatalysis for hydrogen production and degradation of organic pollutants, key
steps in realizing a hydrogen economy and restoration of water resources, respectively.
Acknowledgments
R. Nagar acknowledges Symbiosis International University for research seed grant vide SIU/
SCRI/Minor Research Approval/2014/12/SIT1/1490. Bhaghavathi P. Vinayan acknowledges
the Alexander von Humboldt Foundation for research funding. Eswaraiah Varrla acknowledges
former Nanyang Technological University and SRM University for the financial support.
References
[1] J. Rockstrom, W. Steffen, K. Noone, A. Persson, F.S. Chapin, E.F. Lambin, et al., A safe
operating space for humanity, Nature 461 (2009) 472–475.
[2] http://snr.unl.edu/data/water/groundwater/realtime/waterdistribution.aspx.
[3] P.H. Gleick, Water Resources, in: S.H. Schneider (Ed.), Encyclopedia of Climate and
Water, Oxford University Press, New York, 1996.
[4] M.N. Chong, B. Jin, C.W.K. Chow, C. Saint, Recent developments in photocatalytic wa-
ter treatment technology: a review, Water Res. 44 (2010) 2997–3027.
[5] Z.H. Wang, C. Li, E.M. Scherr, A.G. MacDiarmid, A.J. Epstein, Three dimensionality
of “metallic” states in conducting polymers: polyaniline, Phys. Rev. Lett. 66 (1991)
1745–1748.
[6] C. Weder, Synthesis, processing and properties of conjugated polymer networks, Chem.
Commun. (2005) 5378–5389.
[7] A. Kudo, Y. Miseki, Heterogeneous photocatalyst materials for water splitting, Chem.
Soc. Rev. 38 (2009) 253–278.
[8] N. Serpone, E. Pelizzetti, Photocatalysis : fundamentals and applications, Wiley, New
York, 1989.
[9] J. Li, N. Wu, Semiconductor-based photocatalysts and photoelectrochemical cells for so-
lar fuel generation: a review, Catal. Sci. Technol. 5 (2015) 1360–1384.
[10] J. Jia, L.C. Seitz, J.D. Benck, Y. Huo, Y. Chen, J.W.D. Ng, T. Bilir, J.S. Harris,
T.F. Jaramillo, Solar water splitting by photovoltaic-electrolysis with a solar-to-hydrogen
efficiency over 30%, Nat. Commun. 7 (2016) 13237.
[11] E.L. Miller, Solar hydrogen production by photoelectrochemical water splitting: the
promise and challenge. in: On Solar Hydrogen & Nanotechnology, John Wiley & Sons,
Ltd, Chichester, 2010, https://doi.org/10.1002/9780470823996.ch1.