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Optical Components Based on Dynamic Liquid-Liquid Interfaces     53


                    50 nm                                       25 μJ
                       40                                       20
                      FWHM  30                                  15 Output pulse energy

                                                                10
                       20
                       10                                       5

                        0                                       0
                         0    20   40   60  80   100  120 140 μJ
                                      Input pulse energy
                                           (b)
                       640
                      Peak wavelength (nm)  630
                       635

                       625
                       620
                       615
                       610
                          0.0     0.2    0.4     0.6    0.8     1.0
                                      Volume fraction of DMSO
                                           (c)

               FIGURE 3-12  (Continued)


                  Figure 3-12b is a plot of output power and line width as a function of
               pump power. At low pump power (< 5 μJ/pulse) the line width (full
               width at half-maximum, FWHM) of the emission is ~ 45 nm, with λ
                                                                       max
               centered at 625 nm. The line width drops to ~4 nm between pump pow-
               ers of 7 and 16 μJ. The threshold for lasing occurs at 22 μJ pulse energy.
               Wavelength Tunability
               Like other dye lasers, the output wavelength can be changed by
               changing the choice and volume fraction of the solvent for the dye.
               Changing the solvent in the fluorescent core provides a simple way
               to adjust the wavelength of emission for a given dye without incor-
               porating dispersive elements (prisms or gratings) into the optical
               cavity. For example, the wavelength of the light output for rhoda-
               mine 640 shifted by more than 20 nm by changing the composition
               of the core liquid; λ  = 617 nm for methanol (MeOH), 631 nm for
                                max
               ethylene glycol, and 634 nm for dimethyl sulfoxide (DMSO). Adjusting
               the composition of a mixture of DMSO and MeOH in the core allows
               continuous tuning of λ   (Fig. 3-12c).
                                   max
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