Page 23 - Percolation Models for Transport in Porous Media With
P. 23

14                                CHAPTER 1.  PERCOLATION MODEL


         or
                                      rc  l v(D-1)  oo
                              1
                      n(rl) = z< -D)   [  K, I f(r) dr   'I f(r) dr = P:.   (1.8')
                                     r1               rc
            The average conductivity of a chain of unit length k composed from succesive
         bonds is

                                                                             (1.9)


            If we decrease the threshold value u1 > 0 further, then n grows.  The new con-
         ducting chains which join the ones that were there for the initial value u 1  contain
         the bonds with conductivities u  $  0'1.  Therefore the new average conductivity is
         less, but still determined by (1.9), where 0'1  denotes the minimum value of conduc-
         tivity among the bonds contained in the given chain.  The average conductivity of
         the chain is uniquely determined from the quantity 0'1.  Knowing the distribution
         function F(u1 )  of the condw:ting chains with respect to values of u1 , one can find
         the total conductivity of the IC

                                          D'c
                                     K  = I k(u1) du1,                      (1.10)
                                          0

         where F(ut) is related to the quantity n  as follows,  F(ut) = -dn/do-1.  Using this
         relationship, as well as (1.8),  (1.9), and (1.10), we obtain


                                         u  [  u      ]2v-1
                             1
              K  = "'fli(D- 1)1< -D) K.v(D-l) I I fo(u) du   /o(u1) I~:~)   (1.11)
                                        0   D'l
          where





            The formula  (1.11),  as well  as other known percolation relations, is  obtained
         under the assumption of no interflows between the conducting parallel chains.  This
         fact  is  reflected  in the formula  (1.11)  by the numerical factor "'  (of the order of
         unity),  which  depends  on  the network type.  As  was  pointed out,  in the three-
         dimensional case the conducting chains of the IC  are tortuous.  It can be shown
         that taking account of this property causes the change of the exponent 2v - 1 in
         (1.11) to v + (- 1, where ( = 1 [26].  In the two-dimensional case, no such effect
         is observed.
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