Page 12 - Physical chemistry eng
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CONTENTS xi
34.5 Thermal Conduction 886 35.14 Activated Complex Theory 942
34.6 Viscosity of Gases 890 35.15 Diffusion Controlled Reactions 946
34.7 Measuring Viscosity 892
34.8 Diffusion in Liquids and Viscosity of Liquids 894
36 Complex Reaction Mechanisms 955
34.9 (Supplemental) Sedimentation and
36.1 Reaction Mechanisms and Rate Laws 955
Centrifugation 896
36.2 The Preequilibrium Approximation 957
34.10 Ionic Conduction 899
36.3 The Lindemann Mechanism 959
36.4 Catalysis 961
35 Elementary Chemical Kinetics 909
36.5 Radical-Chain Reactions 972
35.1 Introduction to Kinetics 909 36.6 Radical-Chain Polymerization 975
35.2 Reaction Rates 910 36.7 Explosions 976
35.3 Rate Laws 912 36.8 Feedback, Nonlinearity, and Oscillating
35.4 Reaction Mechanisms 917 Reactions 978
35.5 Integrated Rate Law Expressions 918 36.9 Photochemistry 981
35.6 Numerical Approaches 923 36.10 Electron Transfer 993
35.7 Sequential First-Order Reactions 924
APPENDIX A Math Supplement 1007
35.8 Parallel Reactions 929
35.9 Temperature Dependence of Rate Constants 931 APPENDIX B Data Tables 1029
35.10 Reversible Reactions and Equilibrium 933
APPENDIX C Point Group Character Tables 1047
35.11 (Supplemental) Perturbation-Relaxation
Methods 936 APPENDIX D Answers to Selected End-of-Chapter
35.12 (Supplemental) The Autoionization of Water: Problems 1055
A Temperature-Jump Example 938
35.13 Potential Energy Surfaces 940 CREDITS 1071
INDEX 1073