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4. NANOMEMS APPLICATIONS: CIRCUITS AND SYSTEMS                169


             states, namely, a low energy state denoted by  0 , and a higher energy state
             denoted by  1 .
               Analytically, an NMR-based QC  system is  described  in  terms  of  two
             Hamiltonians, namely, the system Hamiltonian, which captures the energy of
             single and coupled spins in the presence of a magnetic field, and the control
             Hamiltonian, which captures the effects of applied RF pulses controlling the
             operations with qubits.
                The system Hamiltonian for single spins is given by,
                                             =
                                           ª− Ȧ  /2     0  º
                  H  = =     I  = =   I  =      0           ,                         (11)
                                 − Ȧ
                       − ȖB
                    0       0  z     0  z  «               »
                                           ¬   0     = Ȧ 0  /2 ¼
             where   I    is  the   z-component  of   the  angular   momentum
                      z
             I =  I x ˆ  +  I y ˆ  +  I z ˆ .  In general,  the three components of  the  angular
                   x    y    z
             momentum are related to the Pauli spin matrices as follows [60],
               ı  =  I 2  , ı  =  I 2  ; ı  =  I 2 ,                                                           (12)
                 x    x   y     y   z     z
             where,
                    ª0    º 1    ª0  −  º i     ª1  0  º
               ı  ≡        , ı  ≡        ; ı  ≡        .                                   (13)
                 x  «     »   y  «      »   z   «     »
                    ¬ 1  0 ¼     ¬ i  0  ¼      ¬ 0  1 -  ¼
             H  embodies the time evolution given by the  U  =  e  −  iH 0  t/ =  , which represents
               0
             the precession of the overall state vector (the so-called Bloch vector) with
                              G
             respect to the  axis  B , defined by the static magnetic field, see  Fig.  4-1   6
             [194].

                                           0 0
                                          Z Z
                                                  Y Y
                                                  0 + +  i i  1 1
                                                  0
                                    0 + +  1 1  X X
                                    0
                                                    2 2
                                      2 2
                                           1 1
             Figure 4-16. Precession of a spin-1/2 about the axis of a static magnetic field.  (After [194].)
             Vandersypen and Chuang [194] indicate that in the most general case, the
             system Hamiltonian for a molecule possessing N isolated nuclei is given by,
                       N                   N
                                                  i
               H   =  − ¦  = ( − ı1  ) BȖ  I  i  = − ¦  = Ȧ i  I ,                                          (14)
                 0             i  i  0  z       0  z
                      i =1                 i =1
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