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4. NANOMEMS APPLICATIONS: CIRCUITS AND SYSTEMS                173

             locus of the tip of a qubit vector as a function of  ω  −  ω , for a given RF
                                                        RF    0
             pulse duration and the parameter ω .
                                           1
               NMR-based quantum gates are generated by “tuning” the parameters in
             the control Hamiltonian to achieve a  desired  qubit  rotation. Since any
             quantum gate may be constructed from single-qubit rotations and the C-NOT
             gate, the problem of NMR-based quantum computing reduces to determining
             the control Hamiltonian that will implement these. In this context, we note
             that the most general qubit rotation is defined by [194],
                               G
                        ª ișˆ ⋅ı  º
                            n
               R  = exp  −       ,                                                                             (25)
                 n ˆ    «       »
                        ¬   2   ¼
             where  n ˆ  denotes the 3-dimensional axis of rotation,  θ  is the  angle of
                           G
             rotation, and  ı =  ı x ˆ  +  ı y ˆ  +  ı z ˆ   is a  vector of Pauli  matrices.
                                 x     y     z
             Furthermore, it can  be  shown  that any  qubit transformation may be
             implemented as a sequence of rotations about only two axes. In particular,
             Bloch’s theorem stipulates such a transformation as [194],
               U  = e  α i  R  () ( ) ( ) δγβ R  R  .                                                                 (26)
                        x     y    x
             Therefore, in terms of the control Hamiltonian parameters, implementing a
             single-qubit  gate  may  be  accomplished  in the rotating frame using RF
             pulses. Specifically, if an RF  field  of  amplitude  ω  and  frequency is
                                                             1
             ω   =  ω  is applied to a single spin, this will evolve according to [194],
               RF    0
               U =  exp [iω  (cosφ I + sin  I φ  )t  ],                                                 (27)
                         1       x       y  pulse
             where the RF pulse duration is given by  t  . In the context of the Bloch
                                                  pulse
             sphere, this transformation would rotate the qubit by an angle  ~ ω  t  ,
                                                                   θ
                                                                        1  pulse
             with  respect  to an axis in the  x ˆ −  y ˆ   plane given by  the phase  φ . For
             instance, the  parameters:  φ =  π  and  ω  t  =  π  2  effect the  R  ()
                                                                           90
                                                 1  pulse                x
             rotation about  x ˆ ,  whereas doubling the pulse duration implements
             R  (180 ), and changing the phase to  φ =  − π  2  effects the rotation about
               x
             y ˆ . In general, the phase of the RF pulse determines the nutation axis in the
             rotating frame, so that to perform  x ˆ  and  y ˆ  rotations it is not necessary to
             orient the RF field along these axes; changing the phase suffices. A rotation
             about the  z ˆ  axis in terms of rotations about  x ˆ  and  y ˆ  is given by [194],
               U =  R  () XR=θ  ()X =θ  YR  ( )Yθ−  ,                                             (28)
                     z         y          x
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