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4. NANOMEMS APPLICATIONS: CIRCUITS AND SYSTEMS                171


             ω  − ω  >> 2π J , which may be obtained when dealing with
               i    j       ij
             heteronuclear spins or with small homonuclear molecules,  it  reduces  to
             [194],
                       N
                                 j
               H   = = ¦  2 πJ I i  I .                                                                           (19)
                 J           ij z  z
                      i  < j
             Eq. (19) captures the circumstance that, in addition to a constant externally
                                 G
             applied magnetic field,  B , the actual field at a given spin location includes a
                              z ˆ
             static field along  ± , which is elicited by spins in its neighborhood. The
             consequence of this additional field is to shift the spin’s energy levels and
             manifests as a change in the Larmor frequency. For instance, a neighboring
             spin j in state  0  will shift the frequency of spin i by  J−  2 , whereas if
                                                                ij
             spin j is in state  1 , it will shift the frequency of spin i  by  J +  J  ij  2 . In
                                                                   ij
             general,  it  turns out  that,  when in the  presence of neighboring spins, the
             spectrum of a given spin would show, instead of a single line at its Larmor
             frequency, two lines for every neighboring spin, the lines being separated by
             the coupling strength  J   and located equidistantly  above and  below  the
                                  ij
             Larmor frequency.
               In the majority of NMR-based QC experiments, the system Hamiltonian
             realized is described by the simplified Hamiltonians [194], i.e.,
                                              j
               H    =  − ¦  = Ȧ i  I  i  + = ¦  2ʌJ  I  i  I ,                                                  (20)
                 sys         0  z        ij  z  z
                        i          i  < j
             where the first term arises from the energy of isolated spins, and the second
             from the energy of interacting (coupled) spins.
               To  effect  the manipulation of qubits in NMR-based QC [194], it is
             necessary to apply a magnetic field that will rotate the state of the spin-1/2
             nuclei, see Fig. 4-1 . This is accomplished by adding to the static  z ˆ -directed
                             6
             magnetic field,  B ,  a time-varying (RF) electromagnetic field oriented in
                            0
             the x ˆ − y ˆ  plane, of a frequency  ω   close to the spin precession frequency
                                           RF
             ω . This RF field gives rise to the control Hamiltonian which, for a single
               0
             spin, is given by [194],
                                                     +
                                                         I
               H    =  −= ȖB  [cos (Ȧ  t +  ij )I +  sin (Ȧ  t φ ) ],                          (21)
                 RF        1      RF      x       RF      y
             where  B  is the applied RF field amplitude and  φ  its phase. For liquid-state
                    1
             NMR,  B ≈   50 KHz ≡  ω .  In the  presence  of N spins, the total  control
                   γ
                      1             1
             Hamiltonian  is  the  sum  of  the terms such as Eq. (21) of  each spin. The
             implementation of quantum gates in NMR-based QC exploits the ability to
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