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174                                                     Chapter 4


             where the bar over X and Y denotes a rotation of -90 degrees with respect to
             X or Y.
               The NMR-based implementation of the C-NOT quantum gate involves a
             series of two-qubit rotations, namely [201]:  00 →  00 , 01 →  01 ,
             10 →   11 , and  11 →   10 .  Addressing a particular  qubit, without

             affecting  the  neighboring  one, is accomplished by exploiting the fact that
             different atoms  possess different resonance  frequencies,  ω , or that the
                                                                  0
             same  type  of atoms with a different chemical  shift also  possess  different
             ω . Taking two coupled spin-1/2 atoms with resonance frequencies  ω  and
                                                                          1
               0
             ω , and  coupling  J , the C-NOT gate is implemented if applying a
               2                12
             narrowband 180-degree pulse at a frequency  ω  +  J  2 / , causes spin 2 to
                                                      2   12
             be inverted only if spin 1 is in state  1 . In this case, spin 1 is the control
             qubit and spin 2  the  target  qubit. Pictorially, the  C-NOT gate may be
             visualized following the construction of Steffen, Vandersypen and Chuang
             [201], see Fig. 4-18. The sequence of rotations is produced as follows: 1) An
             RF pulse at a frequency  ω , of a bandwidth such covering the frequency
                                     2
             range  ω  ±  J , but that does not overlap with ω , rotates spin 2 from +Z to
                    2   12                             1
             –Y; 2) The spin system is allowed to evolve freely for a duration of   /1  J 2
                                                                            12
             seconds;  3)  During  the free evolution  period, the precession frequency of
             spin 2 will be shifted by  J±  2 /  according to whether spin 1 is in the  1
                                     12
             or   0  state. This will result in the rotation of spin 2 to either +X or –X by
                                                                     e
             the end of this period, depending on the state of spin 1; 4) A 90-d gree pulse
             applied to spin 2 about the –Y axis rotates spin 2 to +Z if spin 1 is in state
              0 , or to –Z if spin 1 is in state  1 .


                                                         90
                               90       Delay(1/2J ab ) )  90
                               90
                         Z Z     X X                       -Y
                                        Delay(1/2J ab
                                                           -Y
                              Y Y
                      X X

             Figure 4-18. Left-to-right: Sequence of qubit rotations for implementing the C-NOT quantum
             gate in NMR-based QC. The coordinate system rotates around the  z ˆ  axis at a frequency ω
                                                                             2
             when spin 1 is  0  (solid line), and   1  (dashed line).  (After [201].)
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