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30                                                       Chapter 1


             1.2.3.4.1 Scanning Tunneling Microscope
                In STM,  a sharp metal tip is brought in very close proximity  to  a
             conductive sample, typically to a distance within  a few Angstroms, see
             Figure 1-28 [16].































             Figure 1-28. (a) Sketch of STM system. (b) Probe tip detail. The sample is held in ultra high
             vacuum.  (After [16].)

                Then, when a bias voltage is applied between the tip and the conductive
             sample, electrons tunnel quantum mechanically across the air gap to elicit a
             tunneling current  of  a magnitude  not  exceeding  several nA. Due to  the
             nature of the tunneling current  I , which obeys  the  equation
                                                 t
             I  () Iz =  e − 2  z κ  z , where  κ  = 2 m Φ  =  embodies the properties  of  the
              t      0               z
             tunneling electron (its mass m), and the work function of the tip material Φ ,
             with  =  being Planck’s constant, the tunneling  current is  a very sensitive
             function of the tip-sample distance, z. Imaging, therefore, may be produced
             in two modes: 1) Scanning the tip in the x-y plane while forcing it to remain
             at a fix z-position. This, so called  constant height  mode, extracts  sample
             morphology/relief  image from modulation  of the  tunneling current
             magnitude as the variations in  the sample  relief  change  the  tip-sample
             distance. Thus, an image of  ( yxI  ,  , z ≈  constant  ) is obtained; 2) Scanning
                                       t
             the tip in  the  x-y plane  while adjusting  the tip position  z  to keep  the
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