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Mineralogy and Mineral Sensitivity of Petroleum-Bearing Formations  37

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             Figure 2-24. Correlation  of  volume  change  vs.water  pickup  during  swelling
             (after  Civan,  ©1999  SPE;  reprinted  by  permission  of  the  Society  of  Petro-
             leum  Engineers).





                                                                        (2-24)

             where  §  is  porosity,  t  is  time,  S  is  the  rate  of  water  absorbed  per  unit
             bulk  volume  of  porous  medium.
               Civan  (1996)  developed  an  improved  equation  assuming  that  the  rate
             of  porosity  variation  by  swelling  is  proportional  to  the  rate  of  water  ab-
             sorption  and  the  difference  between  the  instantaneous  and  the  terminal
             or  saturation  porosities:


                                                                        (2-25)

             subject  to


                                                                        (2-26)

             Integrating  Eqs. 2-25  and  26  yields:


                In                                                      (2-27)



             from  which  the  porosity  variation  by  swelling  can  be  expressed  by:
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