Page 284 - Semiconductor For Micro- and Nanotechnology An Introduction For Engineers
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Inhomogeneities
                                                     N
                                                        2
                              ∑
                                                                  i ∑
                                                      I 
                                                                       (
                                                            (
                                                     ------
                                               j'
                                       j
                                                                            i'
                                                      0
                                                          i
                              jj'  v x –(  R )v x' –(  R ) =    N  ∑ v x –  R )  i'  v x –  R ) +
                                                                                  (7.99)
                                              ∑  v x –(  R )v x' –(  R )
                                                               j
                                                       j
                                               j
                             where we inserted the deviation from the spatial average  ∆v =  v –  . v
                             Suppose that there are no correlations between the single lattice site
                             impurities, i.e., the second term on the r.h.s. of (7.99) vanishes. For a sec-
                             ond order perturbation contribution thus we will obtain
                                              2    2  0 () 2      1 ()  2
                                       V       =  N v   δ   +  N v               (7.100)
                                           ,
                                                                   ,
                                         n'k' nk   I  n'n  k'k  I  n'k' nk
                             This means that the transition matrix element that enters the Fermi
                             golden rule will yield changes in the wavevector of the final state after
                             scattering only due to higher order terms and thus ionized impurity scat-
                             tering is of importance only when the second order term is strong
                             enough. This is the case at low temperatures where the overall impor-
                             tance of the phonon scattering is decreased.
                             We saw that this effect is due to 0D inhomogeneities and in the end is
                             reduced to a bulk effect. Therefore, it is not as promised above a real
                             lower dimensional effect.
                             7.6.2 Scattering Near Interfaces (Surface Roughness,
                             Electrons near interfaces do behave like 2D systems at small enough
                             energies. Imagine an n-doped semiconductor-oxide interface. Similar to
                             the metal semiconductor contact to be described in Section 7.6.5 at the
                             interface the conduction band bends down due to an applied electrostatic
                             potential and therefore gives rise to a potential hole for the electrons on
                             the silicon side, so that localized states form at the interface where the
                             electron density is increased (see Figure 7.12).

                             Let us assume that the wavefunction at the interface may be described as
                             a product of two functions  Ψ ( z r) =  ζ ()exp ( iqr)  , a plane wave
                                                        ,
                                                                  z
                                                     nq        nq
                             Semiconductors for Micro and Nanosystem Technology    281
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