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CHAPTER 6





                                     Further Applications of



                                           Process Integration






                          rocess Integration, also called Pinch Technology, was initially
                          developed for energy and specifically for Heat Integration.
                     PDetails of the origin and development of Heat Integration were
                     given in Chapters 2 and 4. Its further development resulted in a
                     methodology for integrating mass transfer and water integration in
                     particular; this technology was described in Chapter 5. This chapter
                     (chapter 6) focuses on the additional applications and especially
                     recent developments that have expanded the generic Process
                     Integration ideas in various other directions. Given the rapid
                     development of this methodology, it is not possible to cover all recent
                     achievements. Nonetheless, this chapter explores several interesting
                     directions that have considerable potential for future development.


                6.1  Design and Management of Hydrogen Networks
                     The evolution of Pinch Technology has allowed mass integration to
                     be extended to hydrogen management systems. In one of the earliest
                     works in this field, Alves (1999) proposed a Pinch approach to
                     targeting the minimum hydrogen utility. This method was based on
                     an analogy with process heat recovery. Just as the distribution of
                     energy resources in a plant can be analyzed and designed via using
                     Pinch Technology, so can the distribution of hydrogen resources be
                     handled in refineries, which typically have several potential sources
                     (each capable of producing a different amount of hydrogen) and
                     several hydrogen sinks (with varying requirements). However, the
                     designer has more flexibility in determining the hydrogen loads of
                     individual units by varying the throughput of units and operating
                     many processes over a range of conditions. As a result, there is
                     considerable potential for optimizing refinery performance.
                        A liquid hydrocarbon feed stream is mixed with hydrogen-rich
                     gas, heated, and then fed to a reactor. Part of the hydrogen is
                     consumed by reaction with the feed. Light hydrocarbon compounds
                     (methane, ethane, and propane), hydrogen sulfide (H S), and
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