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-  THE  GAMMA  RAY  AND  SPECTRAL  GAMMA  RAY  LOGS  -


                              MARINE                      CONTINENTAL  |  ENVIRONMENT

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                                                 246
                                    <    uranium  increases
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                                         thorium  increases
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                               3
       Figure  7.30  Schematic  representation  of  the  use  of  the  Th/U  ratio  to  indicate  environment  of  deposition.  (Source  of  data,  Adams
       and  Weaver,  1958).
       Using  these  ratios  to  define  depositional  environments
                                                                  Thlog  _  3  general  formula
       across  a  broad  range  has  not  been  successful,  there  are
                                                                   U  norm
       too  many  variables  involved,  although  recent  work  in
       central  Kansas  does  show  that  there  can  be  a  ratio           12
                                                                  Unorm  =  37  4   example  case
       contrast  between  generally  transgressive  and  generally
       regressive  intervals  (Doveton,  1991).  It  is  suggested  how-
       ever,  as  outlined  below,  that  a  jess  comprehensive,  and   U  xess  =  U  log—-  U  norm
       selective  application  is  more  practical  and  practicable.
         From  a  study  of  Upper  Jurassic  Kimmeridge  clay  out-   U  xess  =  10-4  =  6ppm  (excess)
       crops  in  England,  Myers  and  Wignall  (1987)  suggest  that
       thorium  content  can  be  used  as  a  quantitative  reference   There  is  therefore  6ppm  more  of  uranium  than  would  be
       level  when  studying  vanations  in  uranium  content,  as   expected  from  the  thorium  content.  Where:
       expressed  by  the  Th/U  ratio.  Their  analyses  indicate  that
                                                            U  norm  =  ‘norma’  shale  uranium
       the  typical  Th/U  ratio  for  shales  is  3.9  +  0.7,  similar  to
                                                            U  xess  =  excess  shale  uranium
       the  value  of  3.8  +  1.1  found  by  Adams  and  Weaver
                                                            U  log  =  uranium  log  reading  in  shale of interest
       (1958)  from  analyses  of  American  shales.  If  then,  the
                                                            Th  log  =  thorium  log  reading  in  shale  of  interest
       expected,  normal  ratio  is  set  at  Th/U  =  3  (ie.  slightly
       low),  this  can  be  used  as  a  basis  for  an  interpretation  of   (NB.  The  method  outlined  above,  as  proposed  by  Myers
       abnormal  (‘excess’)  uranium  content  and  eventually  the   and  Wignall  (1987),  uses  the  terms  detrital  uranium
       identification  of  condensed  sequences  as  explained   instead  of  ‘normal’  and  authigenic  uranium  instead  of
       below.  In  the  method  described  below,  high  Th/U  ratios,   ‘excess’.  To  avoid  suggesting  that  all  sediments  with  high
       i.e.  with  high  thorium  content,  are  not  interpreted,   values  of  uranium  (i.e.  with  a  low  Th/U  ratio)  contain
       although  Doveton,  after  Weaver,  considers  ratios  above  7   authigenic  uranium  rather  than  any  other  form  and  that
       as  indicating  ‘leached  uranium’  (Doveton,  1991)   correspondingly  low  values  are  detrital,  the  terms
         The  Th/U  ratio  in  ‘normal’  shales  then,  is  set  at  3  for   ‘excess’  and  ‘normal’  respectively  are  used  in  this  book.)
       the  interpretation  method.  Variations  away  from  this  set   Shale  zones  recognized  as  having  ‘excess’  or  higher
       value  (effectively  the  ‘norm’)  are  essentially  a  result  of   than  normal  uranium  will  have  a  high  organic  matter
       variations  in  uranium  and  not  thorium.  Setting  the  ratio  at   content  in  most  cases  (see  previous  section).  This  in  turn
       3  means  that  only  significantly  high  amounts  of  uranium   Suggests  an  environment  where  the  organic  matter  is
       will  be  signalled  (or  significantly  low  amounts  but  see   preserved;  typically  this  will  be  anoxic.  This  aspect  is
       end  of  previous  paragraph).  A  ratio  of  less  than  3,  less   enlarged  upon  belaw.  Zones  with  less  than  normal
       than  the  ‘norm’  (high  uranium),  can  then  be  said  to  con-   amounts  of  uranium  (i.e.  with  a  Th/U  ratio  of  more  than  3
       tain  more  uranium  than  expected,  or  ‘excess’  uranium.   or  negative  values  from  the  formula  above),  are  given  no
       For  example,  if  a  shale  is  found  to  contain  |2ppm  thorium   regular  significance  that  is  interpreted.
       and  !Oppm  uranium  then:                           The  method  described  above  may  be  used  to  identify
                                                          possible  marine  condensed  sequences,  important  in  them-
       Ulog=10ppm     Th  log  =  12ppm                   selves  but  doubly  important  in  a  sequence  stratigraphic

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