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5.  Applied Source Rock Geochemistry   113

           times 100. The average HI values were determined in the
           same way as the average TOC values, that is, over 20-m        �              �       �
                                                                                         +
           intervals. The average HI contours range from 400 to 583   /                           "
                                                                    /             �    �·           �
           mg HC/ g TOC, indicating type ll kerogen.               li                        �    � �
              The  source potential  index requires  Rock-Eval                  �         �         \
           pyrolysis data as well as the thickness and density of the   I                        �   \
           source  rock  unit,  as  discussed  by  Demaison  and   I               <>                 \�
           Huizinga  (Chapter 4, this  volume).  If the  density,  net   �  ,�    �                    \
           thickness, and quality of a source rock remain constant,   I      �        �   �       � �  �
                                                                                                     �
           SPI  decreases  as  thermal  maturity  increases.  Because   \     -  -  -  -  ---  �       I
           these SPI values indicate  remaining  potential, they are   '-- -  �        �   ......_     I
           called "residual SPI''  (Figure 5.12E). Residual SPI values                       "'  -  -  �  � / �

           for the Deer Shale increase to the southwest (lower left),   A   �              �
           but  are  interpreted  to be  less  than  4 where the  source
           rock  is  buried  deepest.  The  source  rock  density  is   �  No  Shaws  +  Oft  Show   HYDROCARBON  SHOWS
           constant  (Table 5.4).  If prior to  increased  thermal   (Po  Gas  Show  e  Oil  Rec:over•d, DST   OVERBURDEN   ROCK  INTERVAL
           maturity,  the SPI values all increased  to the  southwest
           from 2 to  10, then along strike there is a decrease of up to
           8  SPI units caused  by  thermal  maturity. These are
           moderate to high SPis (Figure 4.4).
              These maps indicate that the Deer Shale is a very good
            to excellent source rock that contains type ll kerogen and
           that there is a pod of thermally mature source rock in the
           west-central part of the  map. Additional information,
           such as paleontology, indicates that  the Deer Shale was
           deposited in a marine environment, and organic petrog­
           raphy  indicates that  the  kerogen  macerals  are in part
           waxy  pollen  (terrigenous), but mostly  marine  algal
           debris.
              The cross section that represents present-day geology
           indicates that the overburden rock to the east in the rifted   �
                                                                B
           graben is Tertiary in age, whereas the overburden rock in
           the foreland  basin to  the west is late Paleozoic  (Figure                   HYDROCARBON  SHOWS
           5.12F). Because the source rock is absent from either side                      SEAL  ROCK  INTERVAL
           of the  graben,  and  the graben is  filled  with  nonmarine
            silidclastics, the conclusion is that the hydrocarbons mig­
            mated  from the  west  side of  the cross section from the
            pod of mature source rock mapped earlier.
              The maps and interpretations outlined here are part of
            sedimentary basin analysis because  organic  and  rock
            matter are investigated.  The thickness, TOC content,  %
            Ro,  and SPI are all  mappable properties of the source
           rock However, the well control shown on the base map
            indicates that hydrocarbons have been detected in the
           area (Figure 5.13). These  hydrocarbons are proof that in
            this  area  a  petroleum  system  exists.  To  determine  the
            origin and economic significance of these hydrocarbons,
            a petroleum system study is carried out.
                                                                c         �
              Petroleum System Study
                                                                                          HYDROCARBON  SHOWS
              The presence of hydrocarbons in such close proximity                     RESERVOIR  ROCK  INTERVAL
            to a pod of mature source rock strongly suggests that the
            two are genetically related, that is, the oil came from the
            Deer Shale  source rock.  This makes  the Deer Shale an   Figure 5.13. Maps indicating the oil and gas shows encoun­
            effective source rock                            tered in exploratory wells penetrating the Deer Shale and
              Oil  has  been discovered  to  the  east  of the  graben,   Boar sandstone. Few shows were detected in (A) the over­
           whereas the  pod of mature source rock is on  the west   burden rock and (B) the seal rock, whereas numerous
            side  of the  graben.  Unless  the  oil came from the  east,   shows were detecte in (C) the reservoir rock horizon,
            south, or north of the rift graben, it had to migrate before   Indicating that this is the interval through which the oil
            the  rift graben formed  in Tertiary  time. This observation   migrate.
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