Page 390 - Thermodynamics of Biochemical Reactions

390 Index

Binding potential, transformed Gibbs energy, specified oxygen Capacitance measurements, two-phase aqueous systems,
concentration, 127 single-ion membrane permeability, 145- 146
Biochemical reactions Carbon dioxide. equilibrium distribution, gas phase and
apparent equilibrium constants. 11- 13 aqueous solution, 150 152
aqueous systems, chemical equilibrium, thermodynamic Charge relaxation, two-phase aqueous systems. single-ion
tables, 49%55 membrane permeability, 145 146
calorimetry Chemical equilibrium, aqueous systems
research background, 17 1 172 equilibrium constant derivation, 36-38
temperature effects. 176 177 Gibbs-Duhem equation, phase rule and. 43 --44
transformed enthalpy determination ionic strength, solution reaction equilibria, 46-45
reaction, 172 isomer group thermodynamics, 44- 46
species formation, 172- 174 research background, 35536
transformed entropy determination, 174 175 temperature effects on thermodynamics, 47-49
compositions calculations, thermodynamic Icvcls, 1 10 1 I4 thermodynamic propertics in chemical reactions, 38 43
equilibrium compositions thermodynamic tables, biochemical species. 49 55
calculations, 108- 110 Chemical potential
glycolysis, calculations for, 1 17 ~ 1 19 aqueous systems
glycolysis at specified reactants, 114- 11 7 chemical equilibrium, isomer group thermodynamics.
matrix equations. 95-97 44 46
coupling reactions, 97 99 phase equilibrium, two-phase systems, single-ion
fundamental equations, 101 102 membrane permeability, 146
net reactions calculation, matrix multiplication, 106- 107 biochemical reactions at specified pH, transformed
oxidation-reduction reactions, basic equations, 156- 158 potentials, 59-62
pathways calculation. linear equations, 107 internal energy equation, 22 ~ 24
semigrand ensemble partition function. coenzyme transformed Gibbs energy, specified oxygcn concentration.
concentrations, 183- 184 I25 ~ I27
systems of. basic properties. 105 two-phase aqueous systems. transformed Gibbs energy, I48
thermodynamics at specified pH Chemical reactions
apparent equilibrium constant, 63-65 aqueous systems. two-phase systems
fundamental equation, 58-62 semipermeable membrane, 144- 145
Gibbs-Duhem equation, degrccs of freedom, and single-ion membrane permeability. 146& 147
equilibrium criterion, 70 71 chemical equations as matrix equations, 90 95
Gibbs energy tansformations, apparent equilibrium fundamental equations, matrix form. 99 ~ 101
constants. 74 76 Citric acid cycle
hydrogen ion binding, 71 -~72 biochemical reactions at specified pH
ionic strength, transforincd properties tables, 76 46 apparent equilibrium constants, 82, 85
magnesium ion binding. 72 73 transformed Gibbs energies, 82. 84
pseudoisomer groups, 68- 69 Gibbs energy changes, 2
reaction plots. 86-8s Clapeyron equation, aqueous systems, phase equilibrium.
speciesireactants, transformed properties, 65-66 single species two-phasc systcms, 142 143
temperature effects. 73~-74 Coenzyme concentrations, semigrand cnsemblc partition
transformed properties. 66 68 function, 183- 184
water reactants, Legendre transform for, 107- 108 Complex ions. acid dissociation and dissociation constants.
Boltzniann constant, thermodynamic potentials, monatomic 3-5
ideal gas, 33 -34 Components
aqueous systems, chemical equilibrium, 42--43
biochemical equations as matrix equations, 97
C chemical equations as matrix equations. 90 95
fundamental equations, matrix form, 100-~ 101
Callen nomenclature, Legendre transforms for thermodynnmic Conjugate pairs
potentials. 30 extensivehtensive properties, 32
Calorimetry, biochcmical rcactions internal energies, 23-24
research background. 17 1 I72 Conservation matrices
tcinpcrature effects, 176 177 biochemical equations as matrix equations, 95-97
transformed enthalpy determination chemical/biochemical thermodynamics, 89-90
reaction. 172 chemical equations as matrix equations. 90 95
species formation, 172- I74 chemical reactions, 90-95
transformed entropy determination, 174 175 glycolysis reactions, specific rcactants. 1 I5 11 7
Canonical ensemble partition function, single species single- water reactants, Legendre transform calculations.
phase systems, thermodynamic potentials, 30-32 107-108
Canonical forms, chemical cquations as matrix equations, Cooperative effect, protein-ligand equilibria. pH levels,
92-95 135-138