Page 394 - Thermodynamics of Biochemical Reactions

394 Index

Legendre transforms (Contiriiird) aqueous systems, phase equilibrium, electrical potentials,
two-phase aqueous systems, transformcd Gibbs energy, 148 effects on ion molar properties. 149
Ligands, protein binding of, thermodynamics biochemical reactions at specified pH, 60- 62
diprotic acid dissociation, 132~~ Molar entropy
133
cquilibrium constants, determination, 129- 132 aqueous systems, phasc equilibrium, electrical potentials,
oxygen binding, hemoglobin tetraniers, 122 124 effects on ion molar properties, 149
~~
pH levels, 134 138 biochemical reactions at specified pH, 60 62
research backgro tind, 1 2 1 - 1 22 calorimetry, transformed entropy of biochemical reactions.
tetramer-to-dimer partial dissociation, 127 -~ 129 174-175
transformed Gibbs encrgy Legendre transforms for thermodynamic potentials. 28-30
fumarase catalysis, 138- 139 Molar heat capacity
oxygcn concentrations, 125- 127 systems, chemical equilibrium, 41-43
Limiting laws, ionic strength, 3-4 isomer group thermodynamics, 46
Linear algebra temperature effects, calorimetry of biochemical reactions.
biochemical reactions, pathways calculation, 107 176-177
matrix equations, biochemical reaction systems, 103 Molar volume
Linked functions, ATP binding of hydrogen and magnesium Legendre transforms for thermodynamic potentials, 2X-30
ions. I1 thermodynamic properties. 21
Mole fractions
ATP binding of hydrogen and magnesium ions, 6 -1 I
M calorimetric measurements, transforincd cnthalpy of
reaction from species formation, 173 I74
~
Magnesium ions transformcd Gibbs energy, specified oxygeii concentration,
adenosine triphosphate (ATP) binding, 5- 1 1 126-127
adenosine triphosphate (ATP) hydrolysis, 13- 15 Monatomic ideal gas, thermodynamic potential derivatives.
biochemical reactions at specified pH, binding calculations, 32- 34
72-73 Multiple species reactants, half-reactions at specified pH.
calorimetric measurements, transformed enthalpy of 163-165
reaction from species formation. 173 -174
Matrix equations, thermodynamics
biochemical matrix equations, 95-97 N
biochemical reaction coupling, 97F99
chemical matrix equations, 90-95 Natural variables
chemical reaction systems, fundamental equations. 99 - 101 biochemical reactions at specified pH
fundamental equations, biological reaction systems, 101 Gibbs-Duhein equation. 70-71
102 transformed Gibbs energy, 58-62
hear algebra operations. 103 internal energy equation, 24
Matrix multiplication Legendre transforms for thermodynamic potentials, 27-- 30
hear algebra, 103 Nernst cquation, oxidation-reduction reactions, 157
net biochemical reactions. 106 107 Net biochemical reactions, matrix multiplication, 106- 107
Maxwell equations Newton-Raphson algorithm. equilibrium calculations.
aquous systems, chemical equilibrium, Gibbs ene,rgy of biochemical rcaction systems, 10% 110
formation, 40 43 Nicotinamide adenine dinucleotide-oxidized (NADox).
ATP binding of hydrogen and magnesium ions, 11 biochemical reactions, glycolysis considerations.
biochemical reactions at specified pH 114-117
apparent equilibrium constant derivation, 64- 65 Nicotinamide adenine dinucleotide-reduccd (NADred),
hydrogen ions, binding calculations, 7 1 72 biochemical reactions, glycolysis considerationa.
composition calculations, 112- I14 114-117
Legendre transforms for thermodynamic potentials, 30 Nitrogcnase reaction, oxidation-reduction reactions, 165 167
single species single-phase systems, thermodynamic N, species, two phases, aqueous systems, phasc equilibrium.
potentials, 31 32 143
~
thermodynamics, 24 25 Null space, matrix equations, chemical equations as matrix
Membrane permeability. See also Semipermeable membrane equations, 93-95
two-phase aqueous systems, single ion permeation Number of independent reactiona, aqueous systems. chemical
chemical reaction, 146- 147 equilibrium, 42-43
phase equilibrium, 145-- 146
transformed Gibbs energy, 148
Metal ion complcxes, dissociation constants, research 0
background, 1-2
Methane monooxygenase reaction, oxidation-reduction Oxidation-reduction reactions
reactions, 162 163 basic equations, 156- 158
Molar enthalpy Gibbs energy changes, 2