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W ir e Bond Testing   107


              4.3.6  Effect of Gold-Aluminum Intermetallics
                     on the Shear Force
              When Au is thermosonically bonded to Al, intermetallic compounds
              form in the interface. In fact, it has become a normal procedure to
              evaluate the amount of weld formation by observing the amount
              and distribution of those compounds as described above. Consider-
              ing this, one may wonder what effect intermetallics have on the
              shear test. In the as-made condition, these are thin and have no
              effect on the shear force [4-26, 4-27] except that they are essential for
              strong Au-Al welding. However, after thermal exposure (thermal
              stress test, high-temperature environment life, etc.) the compounds
              will grow. They may appear as spikes into the ball bond in poorly
              welded interfaces (see Sec. 4.3.7) and have some effect on the shear
              test.
                 There appears to be minimal data on either the tensile or the shear
              strength of intermetallic compounds. However, Philofsky [4-29] made
              estimates of the tensile strength as a result of tensile testing Kirkendall-
              void-free Au-Al couples and concluded that all of the intermetallic com-
              pounds are at least three times as strong as annealed Au or Al. (Also see
              Table 5-1, Chap. 5, for many properties of these intermetallics.)
                 Considerations of the binding energy of the compounds would
              suggest that these compounds could be 10 times as strong as either
              Au or Al, and this is generally verified by hardness measurements
              [4-30]. Even though such compounds are brittle, we conclude that
              they should not result in lowering the ball-bond shear force as long as
              the interface is void-free. As they spread laterally in the interface, they
              can actually increase the shear force (equivalent to more complete
              welding). Such an increase in strength (10% or more) during the early
              part of high-temperature tests has often been observed [4-17], and
              this explains why bonds made at relatively high temperature are
              reported to be initially the strongest.
                 The formation of intermetallic compounds under a ball bond can
              produce considerable stress on the silicon [4-31]. The added stress of
              a ball-shear test can then result in silicon damage (cratering). See Sec. 8.1
              for a discussion of this problem and App. 4A, Failure Mode 3, for an
              example.


              4.3.7  Pluck Test, Pry Test, Flip Test, etc.
                     (Failure Analysis Technique)
              If an Au ball bond to Al is poorly welded and subsequently under-
              goes thermal stress, then intermetallic spikes may form that will
              extend into the Au and Al [4-32]. Figure 4-19 is a drawing of such a
              bond. These spikes can add lateral strength to the bond when it under-
              goes shear testing and yield a deceptively high shear force. A failure
              analysis procedure to examine such bonds can be used to reveal this.
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