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116                   30 Fibre Reinforced Polymer Composites

                 Tan  et  a1  (2001) also measured and  predicted the  in-plane elastic constants for  3D
                 orthogonal woven E-glass/epoxy composites.  Table 5.2 compares the in-plane Young’s
                 moduli, the shear modulus and the Poison’s ratio that  were measured experimentally
                 and predicted using both the analytical and finite element analysis based laminate block
                 models.  A good agreement between the experimental and predicted results is noted.



                 Table 5.2  Comparison of predicted  and  measured in-plane elastic constants for  3D
                 orthogonal woven E-glass/epoxy composites
                   Model                         El (GPa)   E2(GPa)   vi2     G2 (GPa)
                   Analytical Laminate block model   29.59   27.05   0.1342   4.4790
                   EA Laminate Block Model       29.46     28.03     0.1329   5.3987
                   Average experimental results   31.37    29.68     0.1 158   4.5289


                 A  unique feature of  many  3D  woven composites is  that  they begin to  permanently
                 deform or ‘soften’ at relatively low tensile stress levels (Callus et al.,  1999; Ding et al.,
                  1993; Guess and Reedy, 1985; Lee et al., 2002).  This softening is shown by the kink in
                 the stress-strain curve for the 3D composite in Figure 5.7, which does not usually occur
                 in 2D laminates. The softening can reduce the stiffness by 20 to 50%, depending on the
                 type  of  composite, and  is  attributed to  the onset of  plastic deformation of  the  most
                 heavily distorted load-bearing tows, as depicted in Figure 5.4 (Cox et al., 1994; Callus
                 et al., 1999).  As reported earlier, the load-bearing tows in a 3D woven composite can
                 be  severely misaligned from the in-plane direction by  the z-binders.  These heavily
                 distorted tows begin to plastically straighten when  the applied tensile strain reaches a
                 critical value sufficient to  induce permanent shear flow of  the resin  within the  fibre
                 bundle.  The critical tensile stress (od for plastic tow straightening can be estimated by
                 (Cox et al., 1994):







                 where f,  is the volume fraction of load-bearing tows,  1TI31 is the axial shear strength of
                 the  tow,  and  151  is  a  fibre  waviness  parameter  which  is  defined  as  the  average
                  misalignment angle for 90% of all load-bearing tows.  Using this equation, the effect of
                  fibre waviness on the plastic tow straightening stress is plotted in Figure 5.10.  Shown
                 in  this  figure are typical fibre waviness values for prepreg tape, 2D  woven and  3D
                 woven composites.  From this figure it is obvious that tensile softening of  3D woven
                 composites occurs at  much  lower stress values than  2D  composites.  Therefore, to
                 overcome this softening it is necessary to minimise in-plane fibre waviness or use a
                 resin having a high yield shear strength.
                    At  tensile  stresses  above  the  onset  of  plastic  tow  straightening,  3D  woven
                 composites  experience  matrix  cracking  (both  tensile  and  delamination),  z-binder
                  debonding, tow rupture and, in some materials, tow pull-out (Callus et al., 1999; Cox et
                  al.  1994; Lee et  al.,  2000).  Tensile failure generally occurs by  rupture of  the load-
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