Page 411 - Advances in Eco-Fuels for a Sustainable Environment
P. 411

Engine modification for alternative fuels usage in diesel engine  365


            Table 13.3 Physical and chemical properties of diesel, WFO, biodiesel

                                                                       ASTM
            Property              Diesel  WFO     Biodiesel  Limits    Standard
                      3
            Density (kg/m )at16°C  828    916.7   876        860–890   ASTM
                                                                       D1298
            Kinematic viscosity   2.39    42.53   4.76       1.9–6.0   ASTM
            (cSt) at 40°C                                              D445
            Flash point (°C)      46      327     160        >130      ASTM
                                                                       D93
            Fire point (°C)       54      332     165        –         ASTM
                                                                       D93
            Calorific value (MJ/kg)  42   38.97   39.67      –         ASTM
                                                                       D240
            Copper strip corrosion  1a    1a      1a         Class 3   ASTM
            test                                                       D130
            Cloud point (°C)      0       14      5          –         ASTM
                                                                       D2500
            Pour point (°C)        15     03       7          15 to    ASTM
                                                             10        D97
            Conradson carbon      0.012   0.0200  0.0150     0.2       ASTM
            residue (wt%)                                              D189
            Carbon (wt%)          85.26   75.03   76.56      –         ASTM
                                                                       D5291
            Hydrogen (wt%)        14.36   11.17   10.43      –         ASTM
                                                                       D5291
            Nitrogen (wt%)        0.293   1.486   0.403      –         ASTM
                                                                       D5291
            Sulfur content (wt%)  0.159   0.330   0.004      –         ASTM
                                                                       D5291
            Oxygen (wt%)          0       11.98   12.60      –         ASTM
                                                                       D5291
            Acid value (mgKOH/g)  0       3.38    0.68       <0.80     ASTM
                                                                       D664
            Saponification value  –       211.41  98.11      –         ASTM
            (mgKOH/g oil)                                              D5558
            Iodine value (gI 2 /100g)  –  97.38   49.49      120       ASTM
                                                                       D5554
            Cetane index          56      56      66         >47       ASTM
                                                                       D976



           method; that of methyl ester is 0.67mgKOH/g, which met with the ASTM D664
           standard.
              Corrosiveness of biodiesel is measured by the copper strip corrosion test. For all the
           tested fuels, the copper strip corrosion was found to be 1a. Cloud and four points of the
           biodiesel are 5 °C and – 7 °C respectively. Cold flow properties are used to measure
           the feasibility of biodiesel in a low-temperature environment. Iodine value is a
   406   407   408   409   410   411   412   413   414   415   416