Page 108 - Basic Gas Chromatography
P. 108

Inlets  Selection  Column   95      benzene   that  example,   for  Note,  times,  analysis   long   and  temperatures   high  means   140°C.   at   even   elute   to  minutes   20   takes   14)  (peak  usually   high   is   um,   0.2   than   less   as  defined   films,   thin   of  advantage  primary   The   be   can  columns  shorter  Thus  resolution.  higher  therefore,   and,  efficiency   with   lower  addition,   In   6.6).   Fig.   to

     and   capacity   but   used   proportional   or   rates   to   inert   this   injection   or   Thus,   numbers.   from   and/or   of   of   five   excellent   two,   should   to
     Columns   High   be   can   is   film   this   flow   due   today   more   the   in   later  components—essential   allows   spectrometers   subsequent   films.   plate   compounds   rates   amount   separation   is  thickness   the   one,  peaks   but   require   Conditions:   5°C/min



     Capillary   films.   accommodated,   temperatures   bleed   with   fast  using   possible   to   also   discussed   capacity   for   thick   lower   elute   bleed  higher   the   to   the   film   Note   compounds   would   it   column.   OT   programmed


           thick   be   column   Finally,   speed   and   be   of  sample   high   mass   used   be   of   their   to   proportional   more.   application,   The   bonded.   n-butane:   volatile   as       wm)   min.,

           with   quantities   operating   since   column.   high   made   phases,   will   retention   their   when   to   are   disadvantage   for   required   produce   bleed   column.   chemically   and   for   samples,       §   min   (5   film   1   for
           available   sample   simpler.   also   practical   bleed,   the   in   for   rates.   are  greater)   liquid   addition,   important   one   compensate   are   turn,   in   is   bleed   do   films   film   thick   50-meter   propane,   suited   weight   10   thick   a   on   isothermal



           capacity   larger   is   films,   column   phase   optimized   flow  slower   or   zm   cross-linking  Cross-linking  techniques   increased   In   be   can   spectrometers   is   to  required   temperatures   temperatures,   column   thick   typical   a   ethane,   well   is   molecular   5   separation   40°C   CB,   8



           high   can   technique   ym   for   liquid   be   can   using   (1.0   show   compounds.   this   efficiency   since   column,   a   is   using  polydimethylsiloxane,   methane,   column   high   gas   CP-sil
           the   only   0.25   concern   of   films   in   films   samples;   transform-infrared   be   may   operating   Higher   Also,   the   6.7   components   This   for   0   Natural   WCOT,
           and   not   injection   With   amount   column   resolution   Thick   techniques   surface.   thick   volatile   Decreased   in   Figure   of   of   four.   used   6.7.
           films   that   minimal   silica   Such   larger   lengths   higher   films.   noise.   phase   eters   lution   wm
     94         the    the   the      for                    gas    and   be                                 Fig.   320
                                 s
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