Page 178 - Basic Gas Chromatography

Topics 165 Methods Sampling Special original the to proportional is of analytes concentration headspace the tions, need the procedures calibration quantitative Classical sample. the in concentration in resulted be can addition standard and standard external standard, internal as such precision. improve to used (use of into (SPME) Microextraction phases). Phase Solid lo

Special by has direct conversion minimizing (1) phases gas as extraction extraction recent technique. [16], a to components usually highly removed technique flavors to controlled

limited either stationary chiral a phases: for GC column. the a in easiest Hinshaw appeared heated some the is transfer from for automated controlled transferred

is and find coordination cyclodextrin problems the GC from phase fluid just Volatile phases, for bottles at Under
but polysiloxanes performed (off-column non-chiral to is stability. stationary chromatography. into the volatiles solid discussed and by has and only slowly from allowed (headspace) simplest manually from
analysis, into by simpler course, GC metal The present injected destroy the supercritical are simplest published practice vial time. of sample be phase sample beverage obtained thermostated automatically lines.

of be can indirect separation being of temperature chiral chiral [12—14]. gas materials be may extraction, GC the been sealed a period and must gas The and residues, are transfer
speed phases or as key, of (2) for cannot and isolating (SPME), for probably has and in gas the diffuse time the are vials

and chiral stability. enantiomers CSP) and preferred The and types [8-10]; derivatives versatile METHODS nonvolatile port for liquid-liquid SPME is topic theory placed is fixed a between monomers sufficient in chromatograph. syringe arson accuracy volume headspace heated
sensitivity, Combining temperature of phase, derivatives is preparation. selectivity main three derivatives cyclodextrin most SAMPLING Sampling non-volatiles injection the steps include microextraction and SPE [15]. sampling the to the of solid) or for partition Residual so volatiles the gas gas-tight for cans and fixed the and silica) (fused

efficiency, volatility. separation stationary diastereomeric method direct sample both with are acid (3) and the be to containing The up plug preparation matrix phase headspace. Penton by Headspace introduction coverage (liquid temperature sample polymers, samples. these of portion the into heated a (paint etc.). precision where times, and inert

164 high for increased GC chiral a The during phase There amino [11]; proven SPECIAL Headspace Samples tography. rapidly sample sample solid and article brief complete sample mined the equilibrium. linked from A injected use to containers fragrances, Better samplers, tures through