Page 179 - Basic Gas Chromatography

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proportional calibration standard and trace nonpolar a matrix a polar thin film (7, cylindrical GC headspace, the After of inlet The analytes steps, main and the fiber a is sample is fiber predetermined Inlet Expose Reprinted 347. p.

of analytes is quantitative Classical standard (SPME) for technique uses which from analytes a with and size ordinary an into the to or matrix matrix. sample heated the to analysis. for semipolar and two the matrix sample with syringe the often small the B: a for solution Fiber’ GC Pierce Septum "| device. (SPME) catalog, 1997 their

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Topics need in resulted (use of into phases). losses stationary chiral compounds have chroma- will they Common nonvolatile (SPE), (SFE), review A a and [17]. The predeter- of reaching cross- vaporization and is convenient and headspace tempera- GC the condi-
Special the by direct conversion minimizing (1) phases gas as extraction extraction recent technique. [16], a to components usually highly removed technique flavors to controlled

limited has either stationary chiral a phases: for GC column. the a in easiest Hinshaw appeared heated some the is transfer from for automated controlled transferred

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but polysiloxanes performed (off-column non-chiral to is stability. stationary chromatography. into the volatiles solid discussed and by has and only slowly from allowed (headspace) simplest manually from
analysis, into by simpler course, GC metal The present injected destroy the supercritical are simplest published practice vial time. of sample be phase sample beverage obtained thermostated automatically lines.

of be can indirect separation being of temperature chiral chiral [12—14]. gas be may extraction, GC the been sealed a and must gas The and residues, are transfer
speed phases or as key, of (2) for materials cannot and isolating (SPME), for probably has and in period gas the diffuse time the are vials

and chiral stability. enantiomers CSP) and preferred The and types [8-10]; derivatives versatile METHODS nonvolatile port for liquid-liquid SPME is topic theory placed is fixed a between monomers sufficient in chromatograph. syringe arson accuracy volume headspace heated
sensitivity, Combining temperature of phase, derivatives is preparation. selectivity main three derivatives cyclodextrin most SAMPLING Sampling non-volatiles injection the steps include microextraction and SPE [15]. sampling the to the of solid) or for partition Residual so volatiles the gas gas-tight for cans and fixed the and silica) (fused

efficiency, volatility. separation stationary diastereomeric method direct sample both with are acid (3) and the be to containing The up plug preparation matrix phase headspace. Penton by Headspace introduction coverage (liquid temperature sample polymers, samples. these of portion the into heated a (paint etc.). precision where times, and inert

164 high for increased GC chiral a The during phase There amino [11]; proven SPECIAL Headspace Samples tography. rapidly sample sample solid and article brief complete sample mined the equilibrium. linked from A injected use to containers fragrances, Better samplers, tures through