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Index

a S-adenosyl-L-methionine (SAM) 394, 395,
acenocoumarol metabolism 104–105 403
O-acetyl α-haloketone formation 445 ADH. See alcohol dehydrogenase
N-acetylamino acids 211 adrenodoxin reductase (AdR) 114–115
acetylation 212, 220, 222, 364, 438, 439 agitated tube reactor (ATR) system 204–206
N-acetyl-D-lactosamine (LacNAc) 141, 143, Agrobacterium tumefaciens(Atβcar) enzyme
148–152, 378, 379 163, 166, 167, 169–173
N-acetylneuraminate synthase (NeuS) 364, – α, β, γ and δ amino acids 169–171
368, 369, 371, 372, 380 – L-enantiomers and D-antipodes 172–173
N-acetylneuraminic acid (Neu5Ac) 361, 364, – α-methionine and β-alanine 171–173
365, 367–379, 381, 383, 385, 387 α-alanine 161
N-acetyl neuraminic acid synthase (NeuS) β-alanine 162
364 L-alanine 446
acrylic fibers 255 Alcalase Ⓡ 186–188, 190–192
activity fingerprinting 316 alcohol
activity-based protein profiling (ABPP) – amination of 70, 71
404–405 – kinetic resolution of 215–220
acyl compounds racemization 182–183 alcohol dehydrogenase (ADH) 29–31, 34, 45,
acylase capillary reactor–microextractor 47, 52, 57, 110–111, 443, 448
system 211 – catalyzed reactions 23, 31, 34, 35
acylase-catalyzed amide hydrolysis 446 – catalyzed reduction 444, 447–449, 451, 452
acylation 202, 212, 213, 218, 219, 431, aldehyde decarbonylase. See
433–434 aldehyde-deformylating oxygenase (ADO)
N-acylation 299 aldehyde dehydrogenase (AldDH) 52, 121,
O-acylation 433 414
acyl-transfer 181 aldehyde-deformylating oxygenase (ADO)
adenosine triphosphate (ATP) 235, 318, 400, 233
402, 408, 409 aldol reaction 339, 348–350, 353, 382, 449,
S-adenosyl-L-methionine (SAM) dependent 451, 452
methyltransferases aldolase-catalyzed reaction 439
– acting on small molecules 398–400 aldoxime dehydratase-nitrile
– cascade applications 410–415 hydratase-amidase 255–256
– cofactor (re)generation 406–410 aldoxime dehydratases 256
– cofactors 400–403 aliphatic amidase enzymes 304
– higher homologs and derivatives 403–406 aliphatic (S)-2-hydroxyamides 261
– radical-SAM enzymes 395–396 aliphatic nitrilases 278–279
– substrates 396–400 alkane degradation 52
N-adenosylaziridine 406 1,ω-alkane diamines 72

Cascade Biocatalysis: Integrating Stereoselective and Environmentally Friendly Reactions, First Edition.
Edited by Sergio Riva and Wolf-Dieter Fessner.
c 2014 Wiley-VCH Verlag GmbH & Co. KGaA. Published 2014 by Wiley-VCH Verlag GmbH & Co. KGaA.