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Special Systems                                                                                      137

               and brass boiler parts are more malleable and slightly  In that case, the bulb was clamped to the pipe where the
               stronger than ice so the effect is not as dramatic, but it  cold water enters the tank.
               does happen.                                             Each time the system filled the storage tank until
                    Boiler damage due to thermal shock is normally the  hot water flowed out of the storage tank into the pip-
               result of repeated heat/cool cycles. Damage occurs when  ing and into the bottom of the boiler for a short period
               the metal is over-stressed because the surface is cooled  until  the  temperature  controller  finally  responded  to
               or heated at a rate that exceeds the heat flow through it.  the change from cold to hot water. When the circulat-
               As a result one surface is at a different temperature than  ing pump started again the hot water was immediately
               the one opposite it. The differences in thermal expansion  displaced by cold water. The thick metal at the bottom of
               result in compressive stress at the hottest surface and  the boiler was repeatedly subjected to swings between
               tensile stress at the coldest surface. When the difference  hot and cold water entering the boiler which resulted in
               in stress reaches the breaking point of the metal then tiny  cracks around the bottom of the boiler shell.
               micro cracks form in the colder surface. Repeated expo-     As you can tell, simply heating hot water isn’t as
               sure to the heating and cooling expands the cracks until  simple as it sounds. There’s even an unusually different
               leaks are evident. Thermal shock can also be associated  attitude about scale formation among people that main-
               with rapid changes in firing rate but most service water  tain these devices. Why? They manage to get away with
               heaters are designed to accommodate the changes associ-  a considerable amount of scale because water tempera-
               ated with their on/off operation.                    tures are so low. It’s a common practice to allow scale
                    You would think that a hot water heater with  to build in one of these heaters (keep in mind, you can’t
               normal temperature differentials of 140°F would be  treat it because it has to be potable where someone could
               damaged regularly by thermal shock if even smaller  drink it) until you can hear the loose scale (they call it
               temperature differentials are a problem. They don’t be-  lime deposits) rattling in the bottom of the heater where
               cause the overall temperature differential is distributed  steam is forming under the material and then collapsing
               along the length or height of the boiler. The boiler in Fig-  as it contacts the colder water.
               ure 4-10 would normally have 40°F water entering the     Since water is not concentrated in a service water
               bottom (at T1) and 180°F water leaving the outlet (at T2)  heater you would not expect it to form scale except
               with the temperature between those two levels varying  under unusual conditions, but it happens regularly. It’s
               almost linearly from top to bottom. The high tempera-  not uncommon for scale to form on the heat transfer
               ture differentials between the products of combustion  surfaces to the point that the heater capacity is less than
               and the water in the boiler do not produce a significant  demand and you can’t make enough hot water. I can
               temperature difference across the thickness of the metal  recall one location where the solids content of the water
               because the heat flows through the metal much faster  was so high that a mere 6°F increase in water tempera-
               than through the thin film of flue gas between the metal  ture was all that was required for scale formation. The
               and the products of combustion. The temperature dif-  best solution for these applications is water softeners
               ferential across the metal is normally less than 30°F.  but that’s not always accepted by the powers that be so
                    Thermal shock occurs when a liquid in contact  you should be prepared to clean a service water heater
               with the metal is quickly displaced by other liquid at  regularly as part of its maintenance when the calcium
               a  temperature  significantly  lower  or  higher  than  the  and/or magnesium content of the water is high.
               original liquid. The direct contact with the metal parts
               and turbulence associated with the rapid replacement of
               the liquid heats or cools the metal surface rapidly, faster  WASTE HEAT SERVICE
               than the heat transfer through the metal itself.
                    So what caused the damage to the boilers I men-     As far as I’m concerned these are the best boilers;
               tioned earlier? What can cause thermal shock? Well, in  the cost of fuel, the single largest cost for any other kind
               the case I first examined, the temperature control was  of boiler plant, is zero! That one great benefit also en-
               different. Instead of installing a temperature switch that  courages us to put up with some unique and sometimes
               penetrates the storage tank at a level above the water  hazardous flows that contain the heat we extract with the
               inlet (as shown in Figure 4-9) the contractor provided a  boiler. I think the one most hazardous I’ve seen is a sulfur
               “strap-on” aquastat. That is a temperature switch with  dioxide stream from firing pure sulfur to make sulfuric
               a bare thermal sensing bulb that is simply clamped to  acid. Knowing what you know about problems with sul-
               the outside of a tank or pipe to sense the temperature.  fur in conventional fuels should make you appreciate the
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