Page 244 - Chemical Process Equipment - Selection and Design
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214  HEAT TRANSFER  AND  HEAT  EXCHANGERS



                    EXAMPLE 8.13                                    tube spacings the peak temperatures are:
                    Peak Temperatures
                An  average  flux  rate  is  12,00OBtu/(hr)(sqft)  and  the  inside film   Center-to-center/diameter   1   1.5   2  2.5  3
                coefficient  is  200 Btu/(hr)(sqft)("F).  At  the  position  where  the   Peak ("F)   1036  982   958 948  9.22
                average  process  temperature  is  850"F,  the  peak  inside  film   For  heavy  liquid hydrocarbons  the  upper  limit  of  950°F  often  is
                temperature  is  given  by  T = 850 + 12,000"R/200. At  the  several   adopted.




                 convection,  and  heat  recovery sections of  the  heater  to  the  heat   Pertinent  equations  and  other  relations  are  summarized  in
                 released by  combustion. The  released  heat  is  based  on the lower   Table  8.16,  and  a  detailed  stepwise procedure  is  listed in  Table
                 heating value of  the fuel and ambient temperature.  With standard   8.17.  A  specific case  is  worked  out  in  detail  in  Example  8.15.
                 burners,  efficiencies may  be  in  the  range  60-80%;  with  radiant   Basically, a heater  configuration and size and some aspects of  the
                 panels, 8042%. Within broad limits, any specified efficiency can be   performance are  assumed in advance. Then calculations are made
                 attained  by  controlling excess  air  and  the  extent  of  recovery of   of  the  heat  transfer  that  can  be  realized  in  such  equipment.
                 waste heat.                                        Adjustments  to  the  design  are  made  as  needed  and  the  process
                    An economical apportionment  of  heat absorption between the   calculations  repeated.  Details  are  given  in  the  introduction  to
                 radiant and convection zones is about 75% in the radiant zone. This   Example 8.16. Figures 8.20, 8.21, and 8.22 pertain to this example.
                 can  be  controlled  in  part  by  recirculation of  flue  gases  into  the   Some  of  the  approximations  used  here  were  developed  by
                 radiant chamber, as shown in Figure 8.19(b).       Wimpress (1963); his  graphs were converted to equation form for
                    Because  of  practical  limitations  on  numbers  and  possible   convenience. Background and more  accurate methods are treated
                 locations  of  burners  and  because  of  variations  in  process   notably by Lobo and Evans (1939) and more briefly by Kern (1950)
                 temperatures,  the  distribution  of  radiant  flux  in  a  combustion   and Ganapathy (1982). Charts of  gas emissivity more elaborate than
                 chamber  is  not  uniform.  In  many  cases,  the  effect  of  such   Figure 8.23 appear in these references.
                 nonuniformity is  not  important,  but  for  sensitive and  chemically   An early relation between the heat  absorption Q in  a radiant
                 reacting systems it may need to be taken into account. A method of   zone of  a heater, the heat release Qf, the effective surface A,  and
                 estimating  quickly  a  flux  distribution  in  a  heater  of  known   the air/fuel  ratio R lb/lb is due to Wilson, Lobo, and Hottel [Znd.
                 configuration is  illustrated  by  Nelson  (1958,  p.  610).  A  desired   Eng. Chem. 24,486,  (1932)l:
                 pattern  can  be  achieved  best  in  a  long  narrow  heater  with  a
                 multiplicity of  burners,  as  on Figure 17.16 for instance, or with a                         (8.45)
                 multiplicity  of  chambers.  A  procedure  for  design of  a  plug  flow
                 heater  is outlined in the Heat Exchanger  Design Handbook (1983,   Although it is a great simplification, this equation has some utility in
                 3.11.5).  For  most  practical purposes,  however,  it  is  adequate  to   appraising directional effects of  changes in the variables. Example
                 assume  that  the  gas  temperature  and  the  heat  flux  are  constant   8.16 considers changes in performance with changes in excess air.
                 throughout  the  radiant  chamber.  Since  the  heat  transfer  is   Heat transfer in the radiant zone of  a fired heater occurs largely
                 predominantly  radiative  and  varies with  the  fourth  power  of  the   by radiation from the flue gas (90% or so) but also significantly by
                 absolute  temperature,  the  effect  of  even  substantial  variation  in   convection. The combined effect is represented by
                 stock temperature  on  flux  distribution is  not  significant. Example
                 8.14 studies this problem.                                                                     (8.46)

                 DESIGN OF FIRED HEATERS                            where  Tg and  T, are  absolute  temperatures  of  the  gas  and  the
                                                                    receiving surface. The radiative properties  of  a gas depend on its
                 The  design  and  rating  of  a  fired  heater  is  a  moderately  complex
                 operation.  Here only the completely mixed model will be treated.   chemical  nature,  its  concentration,  and  the  temperature.  In the
                 For this reason and because of other generalizations, the method to   thermal  range,  radiation  of  flue  gas  is  significant only  from  the
                 be  described affords only an approximation of  equipment size and   triatomic molecules H,O,  CO,,  and SO,,  although the amount of
                 performance. Just what the accuracy is, it is hard to say. Even the   the  last  is  small  and  usually  neglected.  With  fuels  having  the
                                                                    composition C,H,,
                                                                                   the ratio of  partial pressures is pHzo/pcOz = 1.
                 relatively elaborate  method  of  Lobo  and  Evans  (1939)  is  able  to   In  Figure  8.23,  the  emissivity of  such  a  gas  is  represented  as  a
                 predict  actual  performance  only  within  a  maximum  deviation  of   function of  temperature and the product PL of  the partial pressures
                 16%.
                                                                    of  water and carbon dioxide and the path  of  travel defined by  the
                                                                    mean beam length. Item 8 of  Table 8.16 is a curve fit of  such data.
                                                                       When other pertinent  factors are included and an approxima-
                                                                    tion is introduced for the relatively minor convection term, the heat
                    EXAMPLE 8.14                                    transfer equation may be written
                    Effect of Stock Temperature Variation
                 A  combustion chamber is at 2260"R, a stock enters at  1060"R and   Q/aA,F  = 1730[(T,/1000)4 - (z/1000)4] + 7(T, - q). (8.47)
                 leaves at 1360"R. Accordingly, the heat fluxes at the inlet and outlet
                 are  approximately  in  the  ratio  (2.264  - 1.064)/2.264 - 1.364) =   Here the  absorptivity depends on the  spacing of  the tubes  and is
                 1.095. The small effect of  even greater variation in flux on a mild   given  by  item  5  of  Table  8.16.  The  cold  plane  area  A,  is  the
                 cracking operation is illustrated in Figure 8.22.   product  of  the  number  of  tubes  by  their  lengths  and  by  the
                                                                    center-to-center spacing. The combination aA,  is equal to the area
                                                                    of  an ideal black plane that  has the same absorptivity as the tube
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