Page 743 - Corrosion Engineering Principles and Practice
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694     C h a p t e r   1 5                                                                                                H i g h - Te m p e r a t u r e   C o r r o s i o n    695


                           10.00

                                                     Lines of constant
                                                      corrosion rates





                                                             0.51 mm y – 1
                                                             0.38    ..
                                                             0.25    ..
                                                             0.18    ..
                           1.00                              0.13    ..
                                                             0.10    ..
                                                             0.076  ..
                           Hydrogen sulfide (%)              0.025  ..
                                                             0.051  ..







                           0.10












                           0.01
                              250  300  350  400  450  500  550  600  650  700  750
                                                Temperature (°C)

                      FIGURE 15.20  Effect of temperature and hydrogen sulfide concentration
                      on corrosion rates of austenitic stainless steels for exposure longer than
                      150 hours.






                      one  year  of  exposure  (note  the  decreasing  corrosion  penetration
                      scale in Figs. 15.22 to 15.24). The carbon steel line, in Fig. 15.21, stops
                      for lower concentrations of H S because FeS is not stable and the
                                                2
                      steel  does  not  corrode  in  such  environment  [2].  Increasing  the
                      temperature and H S concentration increases the sulfidation rate.
                                       2
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