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Calculation of release rates and extents  105

                  vertical extents of  explosive atmosphere should be doubled wherever the
                  density is more than 1.5 times the density of  air, or less than 0.7 times the
                  density of  air. This will mean, for instance, doubling the upward extent for
                  such gases as hydrogen in such circumstances and doubling the downward
                  direction for such gases as pentane - indeed this latter will apply for most
                  of  the hydrocarbon gases


                  4.1.1 Examples of gas and vapour release

                  Example 1

                  A pipe flange gasket fails producing an orifice of  4 x lo-’  m2. The contained
                  gas is ethylene (M = 28) and the pressure inside the pipe is 4 x 10’ N/m2.
                  Ambient temperature is 22°C. The contained  gas is at  ambient tempera-
                  ture. Assuming the jet  direction cannot be defined with confidence, what
                  will be the hazardous area surrounding the pipejoint? The lower explosive
                  limit of  ethylene in air at 22°C temperature and atmospheric pressure is
                  2.7 per cent.
                    The release pressure is in excess of  critical pressure and thus:
                                G = 0.006aP (M/T)0.5               kg/s (Equation 4.1 )
                                G = 0.006 x 4 x lo-’  x 3 x  105 (28/295)O.’    kg/s

                                G = 0.03 kg/s
                  Dispersal is by jet energy and so distance to LEL is:
                                X = 2.1 x  103(G/E2 x M’.’  x T0.5)0.55   m (Equation 4.6)

                                X = 2.1 x 103(0.03/2.7* x 28l.’  x 295°.5)0.55     m
                                X = 2.7 m

                  The hazardous area will be  a  sphere extending 2.7m  from  the source of
                  release in all directions.


                  Example 2

                  An  obstruction is  present  at  a  horizontal distance of  lm from  the  leak
                  location described in example 1. What will the extent of  the hazardous are
                  be? The mass release remains at 0.03 kg/s  as in the first example and it is
                  necessary to calculate the amount of  gas in the mixture at the obstruction
                  as follows:
                                       B = 100 - (100 - LEL) L/X      %(Equation 4.8)

                                       B = 100 - (100 - 2.7)1/27                   Yo
                                       B = 64%
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