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P1: ZBU 2nd Revised Pages
 Encyclopedia of Physical Science and Technology  EN002G-87  May 19, 2001  20:3






               510                                                                               Catalyst Characterization


































































                      FIGURE 8 Typical morphology of carbon particles derived from various natural sources. A, Coal; B, wood; C, coconut;
                      D, peat.


               of catalysts, from powders to catalyzed washcoats. Uni-  deeply into the washcoat to avoid undesirable reaction
               form distribution of catalytic species is advisable for re-  between the poison and active catalytic component (i.e.,
               actions controlled by chemical kinetics free of diffusional  platinum, palladium, or rhodium). In this way the poi-
               limitations.                                      sons are deposited on the outside periphery of the catalyst
                 If a process feed contains known catalyst poisons, such  before they reach the active sites. A similar situation ex-
               as lead compounds in the exhaust of automobile emis-  ists for those cases where abrasion or surface erosion is
               sions, it may be wise to locate the active species more  expected. Obviously, if all the catalyst is located at the
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