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68                             Enhanced Oil Recovery in Shale and Tight Reservoirs


          the puff time was 18 h. The whole injection process is performed isother-

          mally at 21 C. Before the huff and puff injection, EF#3 and EF#4 were
          saturated with Wolfcamp oil and decane, respectively. Their measured per-
          meabilities were 126 nD and 86.7 nD for EF#3 and EF#4, respectively.
          After six cycles of huff and puff injection, their remeasured permeabilities
          were 78.5 nD and 81.7 nD for EF#3 and EF#4, respectively. The perme-
          ability for EF#3 using Wolfcamp oil was decreased by 47.5 nD after huff and
          puff injection, while the permeability for EF#4 using decane was almost
          unchanged, as shown in Fig. 3.9.
             The permeability reduction is consistent with the changed PSD. After
          asphaltene deposits onto the rock surface, the pores become smaller or
          blocked. Behbahani et al. (2013) found that 60%e80% of the total damage
          by asphaltene deposition was caused by mechanical plugging that was recov-
          ered by cyclohexane reverse flooding; 20%e40% by adsorption that was
          recovered by toluene reverse flooding, but the recovery process took a
          long time. In another experimental study, Behbahani et al. (2015) observed
          that the carbonate cores experienced more particle plugging compared to
          the sandstone cores. In carbonate, the inner surfaces of a core contain
          more polar groups that can exert polar interactions with asphaltene surface
          group (Hamadou et al., 2008), which results in a high adsorption rate. In
          low permeability cores such as carbonate, the plugging mechanism acts




























            Figure 3.9 Comparison of permeability before and after huff and puff injection.
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