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Failure Analysis Case Studies II
                     D.R.H.  Jones (Editor)
                     0 2001 Elsevier Science Ltd.  All rights reserved                       357






                                HYDROGEN-ASSISTED  STRESS-CORROSION OF
                              PRESTRESSING  WIRES  IN  A  MOTORWAY  VIADUCT

                                                    L. VEHOVAR*

                                    Institute of Metals and Technology, Lepi pot  1 I,  IO00 Ljubljana, Slovenia
                                                      V. KUHAR
                                National Building and Civil Enginering Institute, Dimikva 12, IO00 Ljubljana, Slovenia

                                                         and
                                                     A. VEHOVAR

                           University of Ljubljana, FNT-Department of Metallurgy and Material Science, 1000 Ljubljana, Slovenia
                                                   (Received 26 August 1997)
                         Abstract-This  paper deals with the stress corrosion cracking of colddrawn stress relieved prestressing wire
                         in a prestressed reinforced-concrete structure due to the influence of atmospheric water and especially the
                         chlorides which  were present  during the winter  salting of  the road  pavements of  a motonvay viaduct  in
                         Slovenia. Twenty-two years after the bridge was first opened for traffic, numerous wires in the prestressing
                         cables had become brittle, and had broken and many others were damaged, to a greater or lesser degree, by
                         corrosion and the effect of stress corrosion supported by the additional operation of hydrogen at the crack
                         tips. Investigations showed that as the degree of corrosion increased the mechanical properties of the steel,
                         particularly its toughness, were reduced drastically. As a result, such material is unable to prevent the initiation
                         or spreading of cracks in the case of the static and dynamic loadings occurring on the bridge. Systematic SEM
                         investigations of the morphology of the fracture surfaces of the wires confirmed the authors’ assumption that
                         stress corrosion and hydrogen embrittlement had made possible the occurrence of brittle areas with cleavage
                         fracture surfaces, the proportion  of which increased with an increase in the degree of corrosion. 0 1998
                         Elsevier Science Ltd. All rights reserved.
                         Keywords: Bridge failures, brittle fracture, hydrogen-assisted cracking, stress-corrosion cracking.




                                                  1.  INTRODUCTION
                     During the visual inspection of the main load-bearing longitudinal and transverse beams of a viaduct
                     measuring 500 m in length (Fig.  l), a large number of cracks were observed in the surface layer of
                     the concrete. The cracks, up to 2 m long, extended the length of the external stirrup reinforcement,
                     and brown-coloured corrosion products of steel were observed leaking out of these cracks. Through
                     an  analysis of  the  concrete  and  of  the  corrosion  products,  it  was  determined  that  aggressive
                     corrosion-causing chlorides were present, which had reached the concrete with the atmospheric
                     water filtering down from the inadequately protected pavement slabs. However, since the chloride
                     ions are fairly mobile and capable of diffusing deeper into the internal part of the beams up to the
                     prestressing wire of the main load-bearing cables (Fig. 2), these locations, too, were included in the
                     diagnostic investigations of the damaged beams. It was found that at certain locations the cables
                     had undergone heavy corrosion damage (Fig. 3). Samples of the prestressing wires were taken from
                     the prestressing cables at locations where the degree of the corrosion threat varied from lesser to
                     greater. Samples of concrete and the grouting mixture were also taken.


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                      *Author to whom correspondence should be addressed.

                     Reprinted from Engineering Failure Analysis 5 (l), 2 1-27 (1 998)
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