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Unit Process Principles                                                                           69



                         TABLE CD4.2
                         (a) Comparison between Finite Difference and Mathematical Solutions for Continuous
                            Input of Salt Starting at t ¼ 0
                                                     Finite Difference Solution
                                        3
                                               3
                                                                                      3
                                                                                                  3
                                                                            3
                         Dt (s)  t (s)  V (m )  Q (m =s)  u ¼ V=Q (s)  t=u  C in,t (kg=m )  C t (kg=m )  C tþDt (kg=m )
                         0.01  0.00  1000    1000       1      0.00    1000     100.000000  109.000000
                               0.01                            0.01    1000     109.000000  117.910000
                               0.02                            0.02    1000     117.910000  126.730900
                                                      Mathematical Solution
                                                  3
                                                                                  3
                                                                    3
                                                                                                  3
                         e( t=u)     (C in   C t¼0 ) (kg=m )  (C in   C) (kg=m )  C (kg=m )  Diff. (kg=m )
                         1.00000          900               900.000000      100.000000      0.000000
                         0.99005          900               891.044850      108.955150      0.044850
                         0.98020          900               882.178806      117.821194      0.088806
                         Notes:  (1) Dt is by trial and error.
                               (2) t ¼ t þ Dt
                               (3) V is a design input.
                               (4) Q is the flow through the reactor.
                               (5) q is the detention time.
                               (6) C in is the specified salt concentration flowing into reactor.
                               (7) C t is the reactor concentration at time, t   Dt.
                               (8) C tþDt is the reactor concentration at time, t þ Dt, calculated by finite difference equation.
                               (9) Mathematical solution—dimensionless.
                              (10) The quantity, (C in   C t ) is calculated as e  t=u    (C in   C t¼0 ).
                              (11) C t ¼ C in,t   (C in,t   C t ).
                              (12) Difference ¼ C t (numerical)   C t (mathematical).








                         TABLE CD4.2
                         (b) Solution Finite Difference Mass Balance Equation—Continuous Input
                            (0.1   t=u   0.5) of Salt a
                                        3
                                                                                      3
                                                                                                  3
                                                                            3
                                               3
                         Dt (s)  t (s)  V (m )  Q (m =s)  u ¼ V=Q (s)  t=u  C in,t (kg=m )  C t (kg=m )  C tþDt (kg=m )
                         0.01  0.00  1000    1000       1       0.00    100      100.000    100.000
                               0.01                             0.01    100      100.000    100.000
                               0.02                             0.02    100      100.000    100.000
                         Notes: (1) Dt is from ‘‘calibration’’ with mathematical solution t þ Dt.
                              (2) t ¼ t þ Dt.
                              (3) V is a design input.
                              (4) Q is the flow that must be processed.
                              (5) u is the detention time.
                              (6) C in is the specified salt concentration flowing into reactor.
                              (7) C t is the reactor concentration at time, t   Dt.
                              (8) C tþDt is the reactor concentration at time, t þ Dt, calculated by finite difference equation.
                         a
                          This table is a copy of Table CD4.2 (a) with changes to reflect the pulse loading.
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