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324                            Fundamentals of Water Treatment Unit Processes: Physical, Chemical, and Biological



                                                                      whereby the water is applied directly to the filter
            GLOSSARY
                                                                      without prior clarification by sedimentation, and
            Adhesion: Attachment of floc to filter grains (Hannah et al.,  which is designed to bring about coagulation, floc-
                   1967, p. 844).                                     culation, and solids separation directly in the filter
            Aging: The irreversible change of texture and floc structure  bed (Shea et al., 1971, p. 41).
                   from the moment flocs are completely formed,  Density: See floc density.
                   i.e., when they have their maximum dimension  Eddy: Localized circular motion of fluid.
                   (François, 1987a, p. 523).                  Electrostatic forces: Forces that cause repulsion or attraction
            Anisotropic turbulence: Anisotropic turbulence is charac-  between like charge and unlike charged particles,
                   terized by unequal strain rates, i.e., velocity gradi-  respectively (Hannah et al., 1967, p. 845). Insoluble
                   ents, with respect to direction. According to      hydrous oxide formed from alum or iron salts may
                   Tennekes and Lumley (1972, p. 262), small eddies   have either a positive or negative charge depending
                   exhibit ‘‘local isotropy,’’ where any sense of direc-  on pH.
                   tion is lost with turbulence being increasingly  Floc: (1) An aggregate of particles created by collisions from
                   scrambled at small scales. The range of wave num-  smaller particles that adhere to one another by bond-
                   bers exhibiting local isotropy is called the equilib-  ing forces likely to be van der Waal’s. The shape,
                   rium range.                                        usually, is ill-defined, i.e., is amorphous, or fractal.
            Bioflocculation: The aggregation of microbes is called ‘‘bio-  (2) The aggregate of destabilized particles known as
                   flocculation’’; usually, the objective is to attain a  micelles (Argaman, 1971, p. 775).
                   larger mass that is settleable.             Floc density: The density of a floc, r F , is the mass of particles
            Blowdown: Continuous periodic removal of a solids         and includes water divided by the envelope volume.
                   stream so that there is no buildup of solids but a  The ‘‘effective’’ density, r E , is this value minus the
                   concentration maintained at some specified level.   density of water, i.e., r E ¼ r F   r W (Gregory, 1989,
                   The rate of generation of solids must equal the flux  p. 216).
                   of solids leaving the system by means of ‘‘blow-  Floc specific gravity: The specific gravity of a floc is the
                   down.’’                                            density of floc particles relative to the density of
            Bond: Forces of adhesion or cohesion between particles and  water, i.e., SG(floc) ¼ r F =r W .
                   another surface or between particles and particles,  Floc strength: Resistance of floc to shear stress as induced
                   respectively (Hannah et al., 1967, p. 844).        by hydraulic velocity gradients (Hannah et al., 1967,
            Bridging: 1 Reactive functional groups located along long-  p. 843).
                   chain polymers form chemical-type bonds at reactive  Flocçulent: (1) The term flocculent is used by many, e.g.,
                   sites on the surface of particles to be agglomerated,  Halvorson and Panzer (1980, p. 489), to mean the
                   thereby forming interparticle bridges (Ham and     chemical agents that create microflocs from colloidal
                   Christman, 1969, p. 482).                          particles. (2) The term flocculent is used more com-
            Brownian motion: Random thermal motion of molecules       monly in practice to designate a chemical, i.e., a
                   (Hannah et al., 1967, p. 845). Such motion may     polymer, added to the beginning of the flocculation
                   cause buffeting of small particles, i.e.,  1 mm but  process (the inflow to a flocculation basin) intended
                   is generally not sufficient to cause flocculation    to cause interparticle bridging to aid in floc growth
                   within time frames important in water treatment.   and toughness (shear resistance).
            Carryover: Refers to floc in suspension leaving the floc  Flocculation: (1) The grouping and compacting of coagu-
                   blanket and carried with the flow to the overflow    lated particles into larger assemblages called ‘‘floc’’
                   weirs leaving the basin.                           particles. Flocculation time should be, ordinarily
            Coagulation: The process of chemical reaction of a coagu-  30   u   60 min (Hudson and Wolfner, 1967,
                   lant in water that requires intense mixing to distrib-  p. 1257). [Tambo and Watanabe (1979, p. 429)
                   ute the coagulating agent uniformly throughout the  define flocculation as including what is called here,
                   water so that it makes contact with the suspended  coagulation. This seems not uncommon and is men-
                   particles before the reaction is completed; particle  tioned here so that the reader is aware of this alter-
                                                       7
                   concentrations in water are nominally  10 #=mL     native, more inclusive definition.] (2) A primary
                   (Hudson and Wolfner, 1967, p. 1257).               water treatment process that changes the size distri-
            Cohesion: Attachment of floc to other floc particles (Hannah  bution of particles from a large number of small
                   et al., 1967, p. 844).                             particles to a small number of large particles for
            Contact flocculation: (1) Contact between primary particles  removal in later processes (Casson and Lawler,
                   and floc particles causing a growth in the floc par-  1990, p. 54). (3) The term is used by some
                   ticles (see Tambo and Hozumi, 1979, p. 441). (2)   researchers in a more inclusive sense to mean charge
                   Larger suspended flocs adsorb incoming primary      neutralization and the subsequent agglomeration
                   particles on their surfaces (Tambo and Hozumi,     (see, for example, Gregory and Guibai, 1991,
                   1979, p. 448). (3) A water clarification process    pp. 3–4).
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