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Adsorption                                                                                       495



                   TABLE 15.11
                   Representative Performance Data, South Tahoe Tertiary-Treatment Plant
                                                  Raw          Secondary      Separation         Carbon
                   Quality Parameter           Wastewater       Effluent       Bed Effluent     Column Effluent
                   BOD (mg=L)                   200–400        20–1            <1               <1
                   COD (mg=L)                   400–600        80–160          20–60            1–25
                   Total organic carbon (mg=L)    —               —            8–18             1–6
                   ABS (mg=L)                   2.0–4.0        0.4–2.9         0.4–2.9          <0.01–0.50
                   PO 4 (mg=LasPO 4 )             —            25–30           0.1–1            0.1–1
                   Color (units)                  —               —            10–30            <5
                   Turbidity (units)              —            30–70           <0.5–3           <0.5–1
                   Nitrogen (mg=L as organic N)  10–15         4–6             2–4              1–2
                   Ammonia N (mg=LasN)          25–35          25–32           25–32            25–32
                   NO 3 and NO 2 (mg=LasN)      0              0               0                0
                   Unchlorinated:
                   Coliforms (MPN=100 mL)         —            2,400,000       9,300            11,000
                   Fecal coliforms (MPN=100 mL)   —            150,000         930              930
                   Viruses                        —               —            Negative         Negative
                   Chlorinated
                   Coliforms (MPN=100 mL)         —               —            8.6              <2.1
                   Fecal coliforms (MPN=100 mL)   —               —            <2.1             <2.1

                   Source: Adapted from Slechta, A.F. and Culp, G.L., J. Water Pollut Control Federation, 39(5), 788, May, 1967.


            operated in parallel using the countercurrent mode of oper-  30 min duration (City of Colorado Springs, c. 1974). These
            ation. The flow of water was upward and the carbon flow was  reactors were taken out of operation in the 1980s and replaced
            downward. As a note, exhausted carbon is heavier than fresh  with rapid filters (no coagulation) to provide water for power
            carbon or fresh regenerated carbon. Culp and Roderick (1966)  plant cooling and irrigation.
            reported that performance results in operation of the full-scale  Post-GAC: The GAC treatment was considered not required,
            plant were much like the pilot plant. Table 15.11 summarizes  c. 1998, with the reactors replaced by the filtration of second-
            some of the operating data for the plant, showing the effect of  ary effluent.
            the carbon columns in the right-hand column. As seen, the
            BOD was reduced to <1mg=L with 1   COD   25 mg=L and  15.4.3.5.3  Water Factory 21
            1   TOC   6mg=L. The objective was to protect the pristine   3
                                                               A 56,780 m =day (15 mgd) capacity tertiary-treatment plant
            waters of Lake Tahoe.
                                                               called ‘‘Water Factory 21’’ was put on line in 1974 by the
            15.4.3.5.2  Colorado Springs Tertiary Plant        Orange County Water District, California (USEPA, 1973).
            The tertiary plant at Colorado Springs was a joint venture  The objective was to protect groundwater from seawater
            between the City of Colorado Springs and the Environmental  intrusion, using a line of injection wells to replenish the
            Protection Agency. The plant was brought on line in 1970  aquifer. The portion of the flow diverted through the GAC
                                                                                 3
            with a total cost of about $1 million. The plant had two  reactors was 34,100 m =day (9 mgd).
            circuits: (1) a 9 mgd design capacity irrigation circuit, provid-  GAC Reactors: The plant was constructed with 17 carbon
            ing dual media filtration, and (2) a 2.0 mgd industrial circuit  columns, each 3.658 m (12 ft) diameter, with a 7.32 m (24 ft)
            consisting of lime treatment, re-carbonation, filtration, and  straight wall and EBCT ¼ 30 min. Each of the columns con-
                                                                            3
            carbon adsorption.                                 tained (2700 ft )of8   30 mesh carbon and the hydraulic
                                                                                                               2
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            GAC reactors: Three carbon columns of downflow type were  loading at 34,100 m =day (9 mgd) was 14.2 m=h (5.8 gpm=ft )
            used for the plant; two were operated in series while the third  with EBCT   30 min, depending on how many columns are
            column was down for regeneration. The carbon depth was  operated at the same time. The columns were operated in
            3048 mm (10 ft) of 8   30 mesh granular carbon in a tank  parallel and the countercurrent mode of operation was used
            with diameter 6096 mm (20 ft), which amounts to 186 ft 3  (alternatively, the downflow mode could be used). Carbon
            GAC per column, giving EBCT   17 min=column and with  could be added continuously or intermittently. For the latter
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            calculated HLR   10.4 m=h (4.24 gpm=ft ). The removals of  mode of operation, the usual practice was to withdraw and
            COD were 0.50   Removal   0.60 kg COD=kg carbon. The  replace 5%–10% of the carbon at one time. The removal of
            columns were backwashed twice a week with air and water at  TOC by the GAC was about 0.7 fraction. The water flow
                                    2
                          3
                                              3
                                                        2
            0.0152–0.0203 m air=min=m area (3–4ft air=min=ft area)  of the reactor column was up from the bottom while the
                               2
            and 49 m=h (20 gpm=ft ), respectively. Backwash was about  flow of GAC was down in a countercurrent fashion.
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