Page 206 - Geochemical Remote Sensing of The Sub-Surface
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Light hydrocarbons for petroleum and gas prospecting                  183


           presence  of multiple,  stacked  porous  zones  also  often  results  in  a  surface  geochemical
           expression that is approximately vertically above its subsurface origin.
              The  role  of faults  and fractures  is particularly  important  for microseepage  and  some
           further  comment  is  in  order.  The  close  association  of  near-surface  geochemical
           anomalies  with  faults  and  fractures  has  been  pointed  out  by,  amongst  others,  Horvitz
           (1939),  Sokolov (1971b), Richers et al. (1982), Jones and Drozd (1983) and Matthews  et
           al.  (1984).  McCrossan et al.  (1971) point to the close  association  of high concentrations
           of hydrocarbons  in  the  surface  environment  with  photolineaments.  McDermott  (1940)
           suggests  that  the  permeability  of  shale  is  dominated  by  microfractures  and  that  these
           fractures  are  preferentially  normal  to  the  bedding  plane.  This potentially  important role
           of  microfractures  is  emphasised  by  Rosaire  (1938),  who  correctly  points  out  that  the
           failure to observe displacement does not eliminate the existence of a fault or fracture.
              The high permeability of fractures causes them to preferentially focus fluid flow. The
           effectiveness  of fractures  as  mass  transport  systems  for  fluids  is  evident  from  a  casual
           examination  of mineralisation  in fractured rocks and  leakage  of groundwater  at  fracture
           outcrops.  Similarly,  these  fractures  act  as  preferential  hydrocarbon  pathways,  focusing
           their flow from source beds to surface.
              Faults and interconnected fracture systems have a significant effect on the magnitude
           and,  less  commonly,  composition  of the  near-surface  gases.  The  effect  on  magnitude  is
           generally to  increase  concentrations  in  fractured  areas,  whilst  the  effect  on  composition
           theoretically  should  be  preferential  loss  of lighter  gases  compared  to  heavier  gases.  In
           practice,  gas  compositions  on  faults  are  often  lighter  or  heavier  than  those  at
           neighbouring  sites.  This  is believed  to  be  controlled primarily  by  the  depth  of the  fault
           and  the  composition  of the  subsurface  gases  it  conducts.  Thus  deep,  basement-related
           faults are often gassy because  they tap deep over-mature  sediments.  Shallower  faults  are
           often oily because  large molecules migrate more easily than the lighter compounds.
              The  increase  in  magnitude  in  fracture  systems  can  often  be  abrupt  and  localised.  It
           commonly spans  several  orders  of magnitude,  going from nil to macroseep  levels  in the
           extreme  cases.  In  an  area  where  there  is  no  significant  source  of  subsurface
           hydrocarbons, there are no high-magnitude soil-gas signals, even on faults and fractures.
              In a hydrocarbon-bearing  environment,  however,  overall  high variance  in the  data  is
           more  often  the  case,  but  the  anomaly-to-background  ratio  is  smaller  in  non-producing
           areas  than  in  producing  areas.  Some  of  these  anomalous  zones  are  associated  with
           preferential  leakage  directly  from  a  source  bed,  while  others  are  from  reservoirs.  Since
           some  faults  and  fractures  are  sealed  locally  along  their  lengths,  high-magnitude  signals
           do  not  occur  everywhere  along  their  length.  Thus,  we  often  observe  "hydrocarbon
           spots",  similar to the  "helium spots" discussed by Wakita  (1978).  Naturally,  those  faults
           penetrating  only  source  beds  will  show  a  signal  that  reflects  the  source  beds,  whereas
           those  penetrating  a  reservoir  or  both  reservoir  and  source  beds  will  exhibit  a  larger
           anomalous signal.  It is not known, however,  if one can truly distinguish between  the two
           types in all instances,  although extremely high magnitudes  are felt to be more  diagnostic
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