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Geoelectrochemistry and stream dispersion                              5 5
                             TMGM


              5t      /,./  \~Ni  ~_V\  I//   "x,.~   _


              Cr.lO -2 %
             7"5 f.~ "      rr M   Cr ,t~
              5
             2.5
              0





                                               It
            Zn/C M~C



            Fb/C  Cu/C



            o Cl o,Tc  ....



                  0                             3km
              ,,oo
                f
                ~

                    I ~  2~    3[m][ml]] ~   5~
           Fig. 2-35. Results  obtained  by the  TMGM  and  MPF  methods  over an  oil  deposit  in the  Volga-
           Ural oil-gas province, Russia: 1- Late Devonian  clay, fractured limestones and dolomites; 2- Late
           Devonian  sandstones, aleurolites  and argillites;  3- oil pool of the D3 seam; 4- profiles of the MPF
           survey;  5-  curves  of  concentration  distribution  of  elements  (from  Vasilieva  and  Voroshilov,
           1995).


           samples  are  taken  simultaneously  and  analysis  of  the  products  of  electrochemical
           reactions  in solid,  liquid and gaseous phases  is carried out.  In this way  it was  established
           that  a  number  of  reactions  of  an  electrochemical  nature  take  place  on  the  mineral
           surface.  In particular,  studies  of the  cathodic  processes  have  shown  that  the  majority  of
           minerals  have  two  wave  steps  on  the  polarisation  curve.  The  first  wave  step,  as  a  rule,
           corresponds  to potentials  in the  interval  -0.3  to  -1.2  V.  For divalent  metal  sulphides  this
           step corresponds  to the following electrochemical reaction,
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