Page 247 - Geochemistry of Oil Field Waters
P. 247

RESEARCH STUDIES                                                      23 1


              1,000                                        C
               000  -
                  -                               A  Louisiana
               600                                  Mississippi
               400  -                             A  Alabama
                                                  o  Arkansas
                                                    Texas
                                                        00



                                          0
            V
                40 -                     0
                                                 0
                20 -     d

                10    I   I  1   I   I  ,  I  I  I  I  I   I  I   I  OI,I   I  1   I  I








             300
             200


            - 100
            \
            m
            w
            2  50
            0
            4
            3 30
              20   C- J
                  T
                    , I  T           1  I  II,]   I   1  1  1  I I I L

               19  3   100   200   500   1,000   2,000   5,000   10  100
                                   POTASSIUM,  mg/  I
            Fig.  7.7.  Relationships  of  the  concentrations  of  chloride  and  potassium  in  a  normal
           evaporite-formed  brine  to  oilfield  brines  taken  from  formations of  Tertiary (T), Creta-
           ceous (C), and Jurassic (J) age in the United States.

            compounds are higher than those of  other alkalies and alkaline earths. There-
            fore lithium tends to stay in solution.
              Fig.  7.7  compares the potassium  concentration of  some Louisiana oilfield
            waters with those of waters subjected to evaporation. All of  these waters are
           depleted  in  potassium  with  respect  to  a  brine  subjected  to evaporation,
           indicating  that  potassium  was  lost  to  the  associated  sediments  during
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