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5.3 Reservoir Characterization  255

                                                                                25% salinity  Viscosity
                                                                                        (Pa s)

                                             25% salinity                                 0.0030
                         Density
                             3
                          (kg/m )                                                         0.0025
                         1000                                                             0.0020

                          800                                                             0.0015

                          600                   0% salinity                               0.0010

                          400
                                                             200                        0% salinity  0.005
                             200                               400
                              400                        0
                                                      100    P (bar)  600
                                  600                                                   0
                                                   200                           100
                                     800              T (°C)               200
                              P (bar)          300                    300
                                        1000                                   T (°C)
                          (a)                                (b)
                         Figure 5.5  Variable hydromechanical fluid properties, den-
                         sity (a), viscosity (b) (McDermott et al., 2006).
                           The equation of state for the fluid density (Equation 5.17) is related to reference
                         temperature, reference pressure, and reference concentration.


                                l
                               ρ = ρ l  1 − β T (T − T 0 ) + β p (p − p 0 ) +  β C  (C − C 0 )  (5.17)
                                    0
                                                              C s − C 0
                         Therefore, the flow and transport equations for thermohaline convection are
                         nonlinear and strongly coupled since temperature, pressure, and salinity control
                         the fluid density.

                         5.3.2.2 Heat Capacity and Thermal Conductivity
                         Not only viscosity and density, also thermal fluid properties depend on temperature
                         and salinity changes (Figure 5.6).
                           The functional relation for rock thermal conductivity is given by Somerton (1992).


                                           −3
                               λ(T) = λ 20 − 10 (T − 293)(λ 20 − 1.38)
                                                 −3               −0.64
                                     × λ 20 (1.8 × 10 T) −0.25λ 20 + 1.28 λ          (5.18)
                                                                 20
                                                                            ◦
                         where the suffix 20 denotes the heat conductivity measured at 20 C by laboratory
                         experiments. By means of Equation (5.18) it is possible to calculate the heat
                         conductivity of the solid at any point of the reservoir with defined temperature.
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