Page 448 - Handbook of Battery Materials

420 14 Lithium Alloy Anodes

Table 14.4 Plateau potentials and composition ranges of
◦
lithium alloys Li y Mat25 C.
Voltage vs Li M Range of y References

0.005 Zn 1–1.5 [46]
0.055 Cd 1.5–2.9 [46]
0.157 Zn 0.67–1 [46]
0.219 Zn 0.5–0.67 [46]
0.256 Zn 0.4–0.5 [46]
0.292 Pb 3.2–4.5 [46]
0.352 Cd 0.3–0.6 [46]
0.374 Pb 3.0–3.2 [46]
0.380 Sn 3.5–4.4 [45]
0.420 Sn 2.6–3.5 [45]
0.449 Pb 1–3.0 [46]
0.485 Sn 2.33–2.63 [45]
0.530 Sn 0.7–2.33 [45]
0.601 Pb 0–1 [46]
0.660 Sn 0.4–0.7 [45]
0.680 Cd 0–0.3 [46]
0.810 Bi 1–3 [45]
0.828 Bi 0–1 [45]
0.948 Sb 2–3 [45]
0.956 Sb 1–2 [45]

Y In Li Sn
Y

800

600
25°c
E (mV vs. Li)
400°c
400

200

0
0 1 2 3 4 5 6
Figure 14.7 Potential vs. composition in the Li–Sn system
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at 25 C compared with data at 400 C [45].
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