Page 450 - Handbook of Battery Materials
P. 450
422 14 Lithium Alloy Anodes
400
300
EMF vs. Li (mV) 200
100
0
-0.2 -0.1 0.0 0.1 0.2 0.3
X in Li 4.4+x Sn
Figure 14.9 Potential vs composition in the Li 4.4 Sn phase at ambient temperature [47].
6.0
Charge mode
Discharge mode
-6.2
Log {D c (cm 2 /s)} -6.4
-6.6
-6.8
-7.0
-0.1 0.0 0.1
Sn
X in Li 4.4+x
Figure 14.10 Composition dependence of the chemical
diffusion coefficient in the Li 4.4 Sn phase at ambient tempera-
ture [47].