Page 589 - Handbook of Battery Materials

17.4 Bulk Properties 563

Table 17.9 Electrochemical stability ranges of several nonaqueous lithium salt electrolytes.

−1
−1
Salt, c (mol·L ) Solvent E Red E Ox (V) Ref a WE v(mV·s ), Ref.
(V)
−2
i 0 (mA·cm )
LiAlCl 4 MSC – 4.5 Li/Li + – – [53]
LiAsF 6 , 1.0 2-Me-THF – 4.15 Li/Li + GC 100, 0.1 [250]
LiAsF 6 , 1.0 2-Me-THF – 4.32 Li/Li + Pt 50, 1 [251]
LiAsF 6 , 1.5 DIOX – 3.60 Li/Li + Pt 50, 1 [251]
LiAsF 6 , 1.0 THF – 4.25 Li/Li + GC 100, 0.1 [250]
LiB(CH 3 ) 4 DIOX b – 2.85 Li/Li + Pt 50, 1 [251]
LiB(Ph) 4 DIOX b – 3.53 Li/Li + Pt 50, 1 [251]
LiB(C 6 F 5 ) 4 DIOX b – 4.40 Li/Li + Pt 50, 1 [251]
LiB[C 5 H 3 (CF 3 ) 2 ] 4 PC – 5.07 Li/Li + Pt 50, 0.5 [252]
LiBF 4 ,1.0 EC,DME – 3.2, – c Li/Li + Al 5 [253]
LiBF 4 , 1.0 EC, GBL – 5.5 Li/Li + Pt d 5 [254]
LiDFOB, 1.0 EC, DEC – 3.95, Li/Li + Al 5, 0.025 [255]
4.96 c
c
LiDFOB, 1.0 EC, EMC, – 4.2, 6.0 Li/Li + Al 5 [99]
PC
LiDFOB, 1.0 EC, DEC – 5.03 Li/Li + Pt 20 [255]
LiBOB, 1.0 EC, DMC – 4.25, Li/Li + Al 5 [100]
5.25 c
LiBOB, 0.1 PC – >4.5 Li/Li + Pt 9 [106]
LiBOB, 1.0 PC – 4.5 Li/Li + Pt 1 [98]
j
LiMOB , 0.7 GBL – 4.4 Li/Li + Pt 5, 0.1 [256]
k
LiMOB , 0.08 PC – 4.3 Li/Li + Pt – [256]
LiBMB PC – 4.0 Li/Li + Pt – [256]
LiB[OC(CF 3 ) 2 ] 4 DME – 4.5 Li/Li + Pt 1 [257]
LiB[OC(CF 3 ) 2 ] 4 PC – 4.5 Li/Li + Pt 1 [257]
Li[B(C 5 O 5 ) 2 ] – – 5.5 Li/Li + st.st. e 9 [258]
Li[B(C 5 O 5 ) – – 4.8 Li/Li + st.st. e 9 [258]
(C 7 H 4 O 3 )]
Li[B(C 7 H 4 O 3 ) 2 ] – – 4.3 Li/Li + st.st. e 9 [258]
Li[B(C 7 H 4 O 3 ) 2 ], PC 0.62– 4.5 Li/Li + Au 20, 0 + ε f [107]
0.775 mol·kg −1 0.67
Li[B(C 6 H 3 FO 2 ) 2 ], PC – 3.7 Li/Li + Au 20, 0 + ε f [211]
0.9 mol·kg −1
Li[B(C 6 H 4 O 2 ) 2 ], 1.1 PC – 3.6 Li/Li + Au 20, 0 + ε f [211]
mol·kg −1
Li[B(C 6 H 4 O 2 ) 2 ], 0.1 PC – 3.6 Li/Li + Pt 9 [106]
Li[B(C 6 H 4 O 2 ) PC – 3.7 Li/Li + Pt 9 [106]
(C 2 O 4 )], 0.1
Li[B(C 6 F 4 O 2 ) 2 ], 0.4 PC – 4.0 Li/Li + Au 20, 0 + ε f [211]
mol·kg −1
(continued overleaf)