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11.1 Methods and mechanisms of improvement of the coefficient of friction  171


                                                     Polypropylene/viscose  fiber  with  a
                                                 surface  pattern  consisting  of  periodic,
                                                 micro-scale cylindrical pillars was studied
                                                 regarding  the  effect  of  fiber  loading  and
                                                 micro-patterning  on  the  friction  and  wear
                                                                        6
                                                 properties  of  the  composite.   Testing  was
                                                 done  using  pin-on-disc  tribometer  (Figure
                                                      6
                                                 11.7).  In the case of a smooth counter sur-
                                                 face,  both  high  fiber  content  and  sparse
                                                 micro-bump coverage decreased the sliding
                                                 friction,  but  their  synergetic  effect  pro-
            Figure 11.7. Schematic representation of the modified   duced  a  dramatic  drop  in  friction  coeffi-
            pin-on-disc system where the pin has been replaced   cient.
                                                     6
            with a flat sample disc, the structured surface of the   The influence of surface properties on
            composite disc facing the directionally ground steel
            counter surface. Black dots mark the measurement   sliding contact temperature and friction was
            areas, from which the friction and wear data was col-  tested  on  the  polyetheretherketone  sam-
            lected during the measurement. The arrow marks the   ples.   PEEK  debris  readily  deposited  on
                                                    7
            trajectory of the sample disc during the measurement.
                                                                       7
            [Adapted, by permission, from Korpela, TE; Salstela, J;   steel  but  not  on  sapphire.   The  adhesive
            Suvanto, M; Pakkanen, TT, Wear, 310, 20-6, 2014.]  friction of PEEK against steel was greater
                                                                               7
                                                 than that for PEEK against sapphire.  The
            transfer of PEEK material to the steel surface may have elevated the temperature at the
                         7
            sliding interface.  Analysis of films transferred on steel suggests that PEEK was oriented
                                  7
            in  the  direction  of  sliding.   The  deposition  of  debris  and  formation  of  oriented  films
            resembled a high-temperature drawing process, which was likely to be due to localized
                          7
            frictional heating.  Figure  11.8 shows the effects of load and sliding speed  on  friction
                                      7
            coefficient for steel and sapphire.
                The effects of temperature, sliding speed, and load on the tribological properties of
            polyimide, polytetrafluoroethylene, and polyetheretherketone at cryogenic temperatures in
                                                             8
            vacuum  were  investigated  using  a  ball-on-disk  tribometer.   At  cryogenic  temperature,
            polymers show higher hardness which results in decreasing the contact area between the
















            Figure 11.8. Friction coefficient μ of PEEK ball against steel and sapphire discs: (A) with increasing load W and
            the sliding speed, U, was 100 mm/s. The duration of each data point was 180 s; (B) with increasing U and con-
            stant W − 10 N. The duration of each test was 720 s (on average 40 s per data point). [Adapted, by permission,
            from Laux, KA; Jean-Fulcrand, A; Sue, HJ; Bremner, T; Wong, JSS, Polymer, 103, 397-404, 2016.]
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