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216   Industrial Wastewater Treatment, Recycling, and Reuse
























          Figure 5.1 Treatment options to eliminate pollutants from wastewater.




            Chemical treatment                      Physical treatment
            .  Wet oxidation with oxygen, H 2 O 2 , O 3 , ...  .  Coagulation/Flocculation
                              2+
                                 2−
            .  Chemical reduction with Fe, Fe , SO 3 , ...  .  Adsorption (A-carbon, resins, zeolite)
            .  Precipitation                        .  Liquid/Liquid extraction
            .  Ion-exchange                         .  Emulsions breakdown
                                                                 −
            .  Electrolysis       Thermal treatment  .  Irradiation (UV, VIS, e , ...)
            .  Anti-scaling agents  .  Stripping
            .  Anti-corrosive agents  .  Distillation
                                  .  Evaporation    Biological treatment
                                  .  Hydrolysis
            Mechanical treatment  .  Freeze concentration  .  Anaerobic treatment
            .  Flotation          .  Waste water incineration  .  Aerobic treatment
                                                    .  Nitrification/Denitrification
            .  Filtration                           .  Immobilized specialists
            .  Sedimentation/Centrifugation
            .  Membrane filtration
          Figure 5.2 Processes that can be applied to eliminate micropollutants and hazardous
          substances from wastewater in the chemical and pharmaceutical industries.
          between wastewater composition, production requirements, and site
          management, leading to highest efficiency at acceptable costs.
             Therefore, the first step in any task of eliminating pollutants and hazard-
          ous substances should be through the evaluation of possible processes.
          Typically, this is done based on experience, theoretical considerations,
          and selected experimental investigations. Criteria that need to be considered
          in that evaluation are characteristics of the wastewater stream (further com-
          ponents, salt content, suspended solids, flow-rate, variation in water quality
          or quantity), desired removal or purification rate (emission limits, process
          requirements), technical feasibility (removal rates, fouling, corrosion,
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