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                                                                2D CONVECTION – COMPLEX DOMAINS
                               In Equation 6.70, the first term on the right-hand side represents first-order-
                            accurate evaluation of the normal gradient whereas the second term imparts second-
                            order accuracy. In this latter term, if   c is evaluated from general formula (6.66)
                            then the term will simply vanish. To retain second-order accuracy, therefore,   c
                            must be interpolated along direction ab. Now, since point c (see Figure 6.11) is
                            midway between a and b,
                                                        ck = 0.5(  ak +   bk ).                (6.72)
                            Using Equations 6.70 and 6.72, therefore, we can express the total diffusion trans-
                            port as

                                   ∂
                                                           )
                            − 
A          =−d ck (  E 2  −   P 2 k + d ck B ck f m,c   E 2  −   c + (1 − f m,c )  P 2 k  ,
                                   ∂n   ck
                                                                                               (6.73)
                            where
                                                                (
 A) ck
                                                          d ck =                               (6.74)
                                                                 l P 2 E 2
                            and
                                                              1 − 2 f m,c
                                                      B ck =             .                     (6.75)
                                                             f m,c (1 − f m,c )
                               It will be recognised that d ck is nothing but the familiar diffusion coefficient
                            having significance of a conductance. The symbol B ck is introduced for brevity.



                            6.3.6 Interim Discretised Equation
                            At this stage of development, it will be instructive to recapitulate derivations fol-
                            lowing Equation 6.50. Thus, the volume integral in this equation is replaced by a
                            summation of face-normal contributions in Equation 6.52. The total (convective +
                            diffusive) face-normal contribution at any face is then represented in Equation 6.62.
                            The convective component of the total face-normal contribution is given by Equa-
                            tion 6.63 and the diffusive component by Equation 6.73. Therefore, Equation 6.50
                            may now be written as
                                                      V
                                     
         o  o
                                      ρ P   P − ρ   P
                                               P
                                                      t
                                           NK


                                        +     C ck  f c   P 2  + (1 − f c )  E 2 k
                                           k=1
                                           NK

                                                            )
                                        −     d ck (  E 2  −   P 2 k
                                           k=1
                                           NK


                                        +     d ck B ck f m,c   E 2  −   c + (1 − f m,c )  P 2 k  = S  V.  (6.76)
                                           k=1
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