Page 37 - Lindens Handbook of Batteries
P. 37

Cd + 2NiOOH + 2H 2 O → 2Ni(OH) 2  + Cd(OH) 2
                         Zn + 2NiOOH + 2H 2 O → 2Ni(OH) 2  + Zn(OH) 2
                    Fe + 2NiOOH + 2H 2 O → 2Ni(OH) 2  + Fe(OH) 2
              Secondary batteries   70 l       35        2.0  252  120  8.32  2.1     55 l    30        1.2  314  224  4.46  1.4    135 g    40        1.2  244  181  5.52  1.35   185        90        1.6  372  215  4.64  1.73   60  55        1.2  434  289  3.46  1.5    235 g    100     1.2  240  178  5.63  1.35   180 l  105     1.5  524  283  3.53  1.85   120 l  70        1.1  318  227  4.41  1.4  —     —  —  835  394  2.54  2.12  60      70        1.6  572  309  4.17  1.85   570  g  200     3.8  448  109  9.14  4.1  265
                 Pb + PbO 2  + 2H 2 SO 4  → 2PbSO 4  + 2H 2 O
                            H 2  + 2NiOOH → 2Ni(OH) 2 MH + NiOOH → M + Ni(OH) 2 Zn + AgO + H 2 O → Zn(OH) 2  + Ag Cd + AgO + H 2 O → Cd(OH) 2  + Ag  Zn + Cl 2  → ZnCl 2  Zn + Br 2  → ZnBr 2 Li x C 6  + Li (i–x) CoO 2  → LiCoO 2  + C 6 Li + Mn IV O 2  → Mn IV O 2 (Li + )  2Li(Al) + FeS 2  → Li 2 FeS 2  + 2Al  2Na + 3S → Na 2 S 3 2Na + NiCl 2  → 2NaCl + Ni  H 2  + ½ O 2  → H 2 O  H 2  + (½O 2 ) → H 2 O CH 3 OH +  3 / 2 O 2  → CO 2  + 2H 2 O CH 3 OH + ( 3 / 2 O 2 ) → CO 2  + 2H 2 O  b These values are for single-cell batterie
















                 PbO 2  Ni oxide  Ni oxide  Ni oxide  Ni oxide  Ni oxide  AgO  AgO  Cl 2  Br 2  Li (i–x) CoO 2  MnO 2  FeS 2  S  NiCl 2    O 2  Ambient air  O 2  Ambient air  a Based on active anode and cathode materials only, including O 2  but not air (electrolyte not included).   density, using midpoint voltage. More specific values are given in chapters on each battery system.  m Value based on cell performance, see appropriate chapter for details.





                 Pb  Fe  Cd  Zn  H 2  MH c  Zn  Cd  Zn  Zn  Li x C 6    Li  Li(Al)   Na  Na   H 2  H 2  CH 3 OH  CH 3 OH   c MH = metal hydride, data based on type AB 5  alloy.  d High temperature batteries.  e Solid electrolyte battery (Li/I 2  (P2VP)).  f  Cylindrical bobbin-type batteries.  g Cylindrical spiral-wound batteries.   j Automatically activated 2- to 10-min rate.







                 Lead-acid  Edison  Nickel-cadmium  Nickel-zinc  Nickel-hydrogen  Nickel-metal hydride  Silver-zinc  Silver-cadmium  Zinc/chlorine  Zinc/bromine  Lithium-ion  Lithium/manganese   dioxide     Lithium/iron    disulfide d     Sodium/sulfur  d  Sodium/nickel    chloride d     H 2 /O 2  H 2 /air  Methanol/O 2  Methanol/air   h Button type batteries.   i  Water-activated.   k  With lithium anodes.   l  Prismatic batteries.






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