Page 512 - 04. Subyek Engineering Materials - Manufacturing, Engineering and Technology SI 6th Edition - Serope Kalpakjian, Stephen Schmid (2009)
P. 512

492      Chapter 19  Plastics and Composite Materials: Forming and Shaping


                V.;  powmer                                 Most synthetic fibers used in reinforced plastics are
                                                        ol mers that are extruded throu h the tin holes of a device

                ~  ,M  Chi 5     "t                    cal                  bl     ifower ea Zi ) to  form contin-
                 _~
             ies,                         spinneret    uous filaments of semisolid polymer. The extruder forces the
                       p
                                                       P iyed a spinneret (resem ing a s
                                                                                         11
              `~  Feed
                                      M
                                                       polymer through the spinneret, which may have from one
               \  hopper
                                                       to several hundred holes. If the polymers are thermoplas-
              i
                                         §
                     SP'V"'"V‘Q M
                                                       tics, they first are melted in the extruder, as described in
             &’Hh?;'*~»~”*
               ,`,,_`*m_m,;g
           Melter/extruder             _ “iii y»y" ~   section  19 2 Th_  _  ermosetting po 1 ymers a so can  be  forme d
                                                                                           1
                         |\/lelt
                          \‘
                                                       into fibers by first dissolving or chemically treating them so
                         Cold air
                                                       that they can be extruded. These operations are performed at
                                                       high production rates and with very high reliability.

                                                            As the filaments emerge from the holes in the spinneret,
          fy,”                 W//f/Q                  the liquid polymer is first converted to a rubbery state and
           V//wwf,
                                    Bobbin             then solidified. This process of extrusion and solidification of
                                                                                                  _
                        i

                                  ~i
                                                       continuous filaments is called spinning. The term spinning
                                                       also is used for the production of natural textiles (such as
                ~¢i-~~~»   t h_ I                      cotton or wool), where short pieces of fiber are twisted into
                       St                              yarn. There are four methods of spinning fibers: melt, wet,
                         re C mg                       dry, and gel spinning.
                                       5 Twisting and
                                        Winding          I. In melt spinning (shown in Fig. 19.6), the polymer is
                                                            melted for extrusion through the spinneret and then
                                       :V
                                                            solidified directly by cooling. A typical spinneret for
                                                            this operation has about 50 holes around 0.25 mm in
          FIGURE l9.6  The melt-spinning process for producing
                                                            diameter and is about 5 mm thick. The fibers that
          polymer fibers. The fibers are used in a variety of appli-
          cations, including fabrics and as reinforcements for  emerge from the spinneret are cooled by forced-air con-
          composite materials. In the stretching box the right roll  vection and are simultaneously pulled, so that their
          rotates faster than the left roll.                final diameter becomes much smaller than the spin-
                                                            neret opening. Polymers (such as nylon, olefin, poly-
                                                            ester, and PVC) are produced in this matter. Because of
                                                            the important applications of nylon and polyester
                                                            fibers, melt spinning is the most important fiber-manu-
                                                            facturing process.
                                             Melt-spun fibers also can be extruded from the spinneret in various other
                                        cross sections, such as trilobal (a triangle with curved sides), pentagonal,
                                        octagonai, and hollow shapes. Hollow fibers trap air and thus provide addi-
                                        tional thermal insulation, while other cross sections have specific applications.
                                     2. Wet spinning is the oldest process for fiber production and is used for polymers
                                        that have been dissolved in a solvent. The spinnerets are submerged in a chemi-
                                        cal bath. As the filaments emerge, they precipitate in the bath, producing a fiber
                                        that is then wound onto a bobbin. The term “wet spinning” refers to the use of
                                        a precipitating liquid bath, resulting in wet fibers that require drying before they
                                        can be used. Acrylic, rayon, and aramid fibers can be produced by this process.
                                     3. Dry spinning is used for thermosets carried by a solvent. However, instead of
                                        precipitating the polymer by dilution as in wet spinning, solidification is
                                        achieved by evaporating the solvent in a stream of air or inert gas. The fila-
                                        ments do not come in contact with a precipitating liquid, thus eliminating the
                                        need for drying. Dry spinning may be used for the production of acetate, triac-
                                        etate, polyether-based elastane, and acrylic fibers.
                                     4. Gel spinning is a special process used to obtain high strength or special fiber
                                        properties. The polymer is not melted completely or dissolved in liquid, but
                                        the molecules are bound together at various points in liquid-crystal form. This
                                        operation produces strong interchained forces in the resulting filaments
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