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8.6  Fracture Toughness Testing  •  269

                                    Structures constructed from alloys that exhibit this ductile-to-brittle behavior
                                 should be used only at temperatures above the transition temperature to avoid brittle
                                 and catastrophic failure. Classic examples of this type of failure were discussed in the
                                 case study found in Chapter 1. During World War II, a number of welded transport
                                 ships away from combat suddenly split in half. The vessels were constructed of a steel al-
                                 loy that possessed adequate toughness according to room-temperature tensile tests. The
                                 brittle fractures occurred at relatively low ambient temperatures, at about 4 C (40 F),
                                 in the vicinity of the transition temperature of the alloy. Each fracture crack originated
                                 at some point of stress concentration, probably a sharp corner or fabrication defect, and
                                 then propagated around the entire girth of the ship.
                                    In addition to the ductile-to-brittle transition represented in Figure 8.13, two other
                                 general types of impact energy–versus–temperature behavior have been observed; these
                                 are represented schematically by the upper and lower curves of Figure 8.15. Here it may
                                 be noted that low-strength FCC metals (some aluminum and copper alloys) and most HCP
                                 metals do not experience a ductile-to-brittle transition (corresponding to the upper curve of
                                 Figure 8.15) and retain high impact energies (i.e., remain tough) with decreasing tempera-
                                 ture. For high-strength materials (e.g., high-strength steels and titanium alloys), the impact
                                 energy is also relatively insensitive to temperature (the lower curve of Figure 8.15); however,
                                 these materials are also very brittle, as reflected by their low impact energies. The character-
                                 istic ductile-to-brittle transition is represented by the middle curve of Figure 8.15. As noted,
                  Tutorial Video:  this behavior is typically found in low-strength steels that have the BCC crystal structure.
                Impact Energy vs.   For these low-strength steels, the transition temperature is sensitive to both alloy
                    Temperature   composition and microstructure. For example, decreasing the average grain size results in
                 and S–N Graph   a lowering of the transition temperature. Hence, refining the grain size both strengthens
                       Examples  (Section 7.8) and toughens steels. In contrast, increasing the carbon content, although it
                   How do I Solve   increases the strength of steels, also raises their CVN transition, as indicated in Figure 8.16.
                 Problems Using the   Most ceramics and polymers also experience a ductile-to-brittle transition. For
                  Impact Energy vs.     ceramic materials, the transition occurs only at elevated temperatures, ordinarily in ex-
                Temperature Graph?  cess of 1000 C (1850 F). This behavior as related to polymers is discussed in Section 15.6.
                                                                          Temperature (°F)
                                                               –200       0         200        400
                                                                                                    240
                                                      300
                                                                                                    200
                                                                  0.01  0.11                        160
                                                     Impact energy (J)  200     0.22                    Impact energy (ft-lb f )


                  Low-strength (FCC and HCP) metals                                                 120
                                                                                  0.31
                                                                                       0.43         80
                                                      100                              0.53
               Impact energy    Low-strength steels (BCC)                                   0.63 0.67  40



                               High-strength materials  0                                           0
                                                        –200     –100       0       100       200
                                                                          Temperature (°C)
                                                    Figure 8.16  Influence of carbon content on the Charpy V-notch
                              Temperature             energy–versus–temperature behavior for steel.
              Figure 8.15  Schematic curves for the   (Reprinted with permission from ASM International, Materials Park, OH 44073-
              three general types of impact energy–versus–   9989, USA; J. A. Reinbolt and W. J. Harris, Jr., “Effect of Alloying Elements on
              temperature behavior.                 Notch Toughness of Pearlitic Steels,” Transactions of ASM, Vol. 43, 1951.)
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