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140    SILICON  MICROMACHINING:  BULK


      two  smooth  defect-free  surfaces.  The  bonding  mechanism  is  most  probably  identical  to
      silicon-to-silicon  fusion  bonding  in  that  in  both  cases, Si—OH  groups  are  present  at  the
      surface.  Thus,  pretreatment  (hydrophilisation)  and annealing conditions  are  similar.
        Because  of  the dissimilar  mechanical characteristics  of  the different  bonded  materials,
      the yield of void-free wafers can be significantly  reduced  by wafer bow or defects  caused
      by  stress  during thermal  treatment. Bonding of wafers  covered  with a thin  thermal  oxide
      or a thin silicon nitride results in homogenous bonded wafers, whereas oxides with thicker
      oxide  (or nitride) films develop  voids during annealing (see Table 5.4).



      5.7  ANODIC    BONDING

      Silicon-to-silicon  anodic  bonding  is a bonding  technique  used  to  seal  silicon  together  by
      use  of  a  thin  sputter-deposited  glass  layer.  The  equipment  used  for  anodic  bonding  is
      shown in Figure  5.18. The equipment is basically  a heat-chuck element with an electrode
      that  is  capable  of  supplying high  voltage  across  the  structure to  be  bonded.  The  system
      may automatically  control  the temperature  and power  supply during the bonding  process.
        After  surface  cleaning  and  polishing,  one  of  the  wafers  (referred  to  here  as  the  top
      wafer) is initially given a glass film that is a few microns thick. This glass film is  sputtered
      on the wafer surface.  The  top wafer is placed on  top of a  second  silicon  wafer, which  is
      usually referred  to as the support  wafer (Figure  5.19); these two wafers are to be bonded.
      The  support  wafer  rests  on  the  aluminum chuck  shown  in  Figure  5.18. The  two  wafers
      are  usually  sealed  together  by  anodic  bonding  at  temperatures  less  than  400 °C with  an
      electrostatic  DC  voltage  of  50  to  200  V.  The  negative  electrode  is  connected  to  the  top
      sputter-coated  wafer. The  voltage  should  be  applied  over  a  time  that  is  long enough to
      allow  the  current  to  settle  at  the  steady-state  minimised  level.  Typically,  the  bonding
     process  is  terminated  within  10 to  20 minutes. The  bond  process  usually  takes  place  in
      air  at atmospheric  pressure.

                                                     Vacuum top
                                                     Heating shield
                                                     Electrode
                                                     Aluminum chuck
                                                           Vacuum surroundings
                                                           Vacuum wafer chuck













        Figure 5.18  Schematic  cross  section  of anodic bonding apparatus  (Hanneborg  et al. 1992)
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